2,3-二甲基-1,3-丁二烯合成路线 （共 777 条）
反应条件
in cyclohexane
byproducts: Me3SiSiMe3; Irradiation (UV/VIS); Solns. of (Me3Si)2GePh2 in cyclohexane readily undergo photolysis to diphenylgermylene and hexamethyldisilane, when irradiated by an array of low pressure Hg lamps through quartz vessels.; The yields are obtained by (1)H NMR integration.;
参考文献
Konieczny, Stanislaw; Jacobs, S. Joshua; Wilking, Janet K. Braddock; Gaspar, Peter Paul
Journal of Organometallic Chemistry, 1988 , vol. 341, p. C17 - C22
参考文献
Hammond, Philip J.; Scott, Graham; Hall, C. Dennis
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1982 , p. 205 - 210
反应条件
unter Zusatz eines Polymerisationsinhibitors und anschliessender Hydrolyse;
参考文献
Du Pont de Nemours and Co.
Patent: US26633737 , 1951 ;
反应条件
1.) 680 deg C, 5.1E-4 Torr, 2.) -50 deg C; Multistep reaction;
参考文献
Lasne, M. C.; Ripoll, J. L.; Denis, J. M.
Tetrahedron, 1981 , vol. 37, p. 503 - 508
反应条件
1: 51 percent / 50percent NaOH / triethylbenzylammonium chloride / ethanol / 16 h / 25 °C
2: 40 percent / Zn, conc. HCl / ethanol / 10 - 15 °C
3: 61 percent / potassium tert-butoxide / dimethylsulfoxide / 2 h / 40 °C
View Scheme
参考文献
Yakushkina,N.I.; Bolesov,I.G.
Zhurnal Organicheskoi Khimii, 1979 , vol. 15, # 5 p. 954 - 961,853 - 859
反应条件
hydrogenchloride
T=-20 - -15°C; und Behandeln des Reaktionsprodukts mit Aethylmagnesiumbromid in Aether bei -30grad bis -20grad;
参考文献
Lewina et al.
Doklady Akademii Nauk SSSR, 1950 , vol. 75, p. 39,41
Chem.Abstr., 1951 , p. 4637
反应条件
lanthanum trifluoromethanesulphonate
T=20°C; hetero-Diels-Alder reaction; 0.5 h;
参考文献
Curini, Massimo; Epifano, Francesco; Marcotullio, Maria Carla; Rosati, Ornelio
Heterocycles, 2001 , vol. 55, # 8 p. 1599 - 1604
参考文献
Baranger; Levisalles
Bulletin de la Societe Chimique de France, 1957 , p. 704,707
Show Details
Skwartschenko et al.
Vestnik Moskovskogo Universiteta, 1957 , vol. 12, # 3 p. 169,171, 173
Chem.Abstr., 1958 , p. 6358
反应条件
in cyclohexane
Irradiation (UV/VIS); Photolyzing with a 110-W medium-pressure Hg arc lamp;
参考文献
Mochida, Kunio; Wakasa, Masanobu; Nakadaira, Yasuhiro; Sakaguchi, Yoshio; Hayashi, Hisaharu
Organometallics, 1988 , vol. 7, p. 1869 - 1871
反应条件
in benzene
T=135°C; 32 h;
参考文献
Carr, Richard V. C.; Paquette, Leo A.
Journal of the American Chemical Society, 1980 , vol. 102, # 2 p. 853 - 855
