in water; acetone
byproducts: sodium 2,4-dimethylbenzenesulfonate; a soln. of NaOAc in H2O added to a soln. of Bi compd. in acetone; filtered, dried, extd. (petroleum ether and H2O); the water-insol. ppt. recrystd. (toluene);
参考文献
Sharutin; Egorova; Sharutina; Ivanenko; Pavlushkina; Gerasimenko; Pushilin
Russian Journal of General Chemistry, 2004 , vol. 74, # 9 p. 1359 - 1364
→
反应条件
in diethyl ether
mixt. of (PhMe)5Sb and Bi sulfonate in ether kept for 48 h at 20°C; ppt. filtered, washed (hexane), dried; ethereal and hexane soln. evapd.,recrystd. from EtOH;
参考文献
Sharutin; Egorova; Pavlushkina; Ivanenko
Russian Journal of General Chemistry, 2002 , vol. 72, # 12 p. 1925 - 1926
in benzene
byproducts: (CF3)2C(C6H4)(Cl)(OCOC6H4OCH3); inert gas; addn. of p-methoxybenzoyl chloride at room temperature; stirring for 10 h under reflux;; thin layer chromatography (ethyl acetate:hexane=1:5);;
