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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
紫草烷
合成路线
(共 9 条)
88818-30-8
→
反应条件
517-90-8
紫草烷
+
64981-69-7
反应条件
aluminium trichloride in dichloromethane 1 h; Ambient temperature;
参考文献
Terada; Tanoue; Hatada; Sakamoto
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 1 p. 205 - 213
517-89-5
紫草素
→
反应条件
517-90-8
紫草烷
反应条件
hydrogen; acetic acid; platinum(IV) oxide
参考文献
Sankawa; Ebizuka; Miyazaki; Isomura; Otsuka
Chemical and Pharmaceutical Bulletin, 1977 , vol. 25, # 9 p. 2392 - 2395
15013-16-8
5,8-二甲氧基-1,4-萘二酮
→
反应条件
517-90-8
紫草烷
反应条件
1: 48 percent / 40percent NaOH, Na2S2O4 / methanol; H2O / 8 h / Heating 2: 99 percent / POCl3 / CHCl3 / 6 h / Heating 3: 95 percent / tetrahydrofuran / 3 h / Ambient temperature 4: 52 percent / cerium(IV) ammonium nitrate / acetonitrile; H2O / 0.5 h / 10 - 20 °C 5: 26 percent / AlCl3 / CH2Cl2 / 1 h / Ambient temperature View Scheme
参考文献
Terada; Tanoue; Hatada; Sakamoto
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 1 p. 205 - 213
10075-63-5
1,5-二甲氧基萘
→
反应条件
517-90-8
紫草烷
反应条件
1: 58 percent / Br2 / CCl4 / 0.5 h / 70 °C 2: 84 percent / CuI / dimethylformamide; methanol / 30 h / Heating 3: 99 percent / POCl3 / CHCl3 / 6 h / Heating 4: 95 percent / tetrahydrofuran / 3 h / Ambient temperature 5: 52 percent / cerium(IV) ammonium nitrate / acetonitrile; H2O / 0.5 h / 10 - 20 °C 6: 26 percent / AlCl3 / CH2Cl2 / 1 h / Ambient temperature View Scheme
参考文献
Terada; Tanoue; Hatada; Sakamoto
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 1 p. 205 - 213
10075-68-0
→
反应条件
517-90-8
紫草烷
反应条件
1: 99 percent / POCl3 / CHCl3 / 6 h / Heating 2: 95 percent / tetrahydrofuran / 3 h / Ambient temperature 3: 52 percent / cerium(IV) ammonium nitrate / acetonitrile; H2O / 0.5 h / 10 - 20 °C 4: 26 percent / AlCl3 / CH2Cl2 / 1 h / Ambient temperature View Scheme
参考文献
Terada; Tanoue; Hatada; Sakamoto
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 1 p. 205 - 213
88818-38-6
→
反应条件
517-90-8
紫草烷
反应条件
1: 84 percent / CuI / dimethylformamide; methanol / 30 h / Heating 2: 99 percent / POCl3 / CHCl3 / 6 h / Heating 3: 95 percent / tetrahydrofuran / 3 h / Ambient temperature 4: 52 percent / cerium(IV) ammonium nitrate / acetonitrile; H2O / 0.5 h / 10 - 20 °C 5: 26 percent / AlCl3 / CH2Cl2 / 1 h / Ambient temperature View Scheme
参考文献
Terada; Tanoue; Hatada; Sakamoto
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 1 p. 205 - 213
88818-28-4
1,4,5,8-四甲氧基萘-2-甲醛
→
反应条件
517-90-8
紫草烷
反应条件
1: 95 percent / tetrahydrofuran / 3 h / Ambient temperature 2: 52 percent / cerium(IV) ammonium nitrate / acetonitrile; H2O / 0.5 h / 10 - 20 °C 3: 26 percent / AlCl3 / CH2Cl2 / 1 h / Ambient temperature View Scheme
参考文献
Terada; Tanoue; Hatada; Sakamoto
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 1 p. 205 - 213
168153-84-2
→
反应条件
517-90-8
紫草烷
反应条件
1: 52 percent / cerium(IV) ammonium nitrate / acetonitrile; H2O / 0.5 h / 10 - 20 °C 2: 26 percent / AlCl3 / CH2Cl2 / 1 h / Ambient temperature View Scheme
参考文献
Terada; Tanoue; Hatada; Sakamoto
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 1 p. 205 - 213
43043-74-9
去氧紫草素
→
反应条件
517-90-8
紫草烷
反应条件
hydrogen; platinum(IV) oxide
参考文献
Shukla,Y.N. et al.
Indian Journal of Chemistry, 1973 , vol. 11, p. 528 - 529