1: 6.5 g / sodium azide / dioxane; H2O / Ambient temperature
2: toluene / 3 h / Heating
3: 80 percent / 3 h / Heating
4: 1.) sodium, liquid ammonia, 2.) pyridine / 1.) methanol, 2.) CH2Cl2, 0 deg C, 2 h
View Scheme
参考文献
Chadwick, Derek J.; Hodgson, Simon T.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 1 p. 93 - 102
Chadwick, Derek J.; Hodgson, Simon T.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 1 p. 93 - 102
→
反应条件
in dichloromethane
crystn. from THF/OEt2;
参考文献
Straus, Daniel A.; Zhang, Cheng; Tilley, T. Don
Journal of Organometallic Chemistry, 1989 , vol. <C> 369, p. C13 - C17