in dichloromethane
Kinetics; byproducts: H2O; to soln. of HCo(CO)4 in CH2Cl2 added Ph3COH in the same solvent under CO at 0 or 20°C in presence of catalytic amts. of HBF4*Et2O, quenched with NH2CH2CH2NH2;
参考文献
Matsui, Yasushi; Orchin, Milton
Journal of Organometallic Chemistry, 1982 , vol. 236, # 3 p. 381 - 384
Samanamu, Christian R.; Amadoruge, Monika L.; Yoder, Claude H.; Golen, James A.; Moore, Curtis E.; Rheingold, Arnold L.; Materer, Nicholas F.; Weinert, Charles S.
Organometallics, 2011 , vol. 30, # 5 p. 1046 - 1058
Samanamu, Christian R.; Amadoruge, Monika L.; Yoder, Claude H.; Golen, James A.; Moore, Curtis E.; Rheingold, Arnold L.; Materer, Nicholas F.; Weinert, Charles S.
Organometallics, 2011 , vol. 30, # 5 p. 1046 - 1058
Samanamu, Christian R.; Amadoruge, Monika L.; Yoder, Claude H.; Golen, James A.; Moore, Curtis E.; Rheingold, Arnold L.; Materer, Nicholas F.; Weinert, Charles S.
Organometallics, 2011 , vol. 30, # 5 p. 1046 - 1058
isopropyl-benzene
T=153°C; 6.5 h; also chloride salt, various reactants, other times, other temperatures, other products; Product distributionMechanism;
参考文献
Huszthy, Peter; Izso, (nee Gergacz) Gyoengyi; Lempert, Karoly; Kajtar-Peredy, Maria; Gyoer, Miklos; et al.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1989 , p. 1513 - 1520
in various solvent(s)
T=153°C; 124 h; variation of conditions, other solvent t-BuPh; also with triphenylmethyl bromide and addition of D2O; MechanismProduct distribution;
参考文献
Huszthy, Peter; Kajtar-Peredy, Maria; Lempert, Karoly; Hegedues-Vajda, Judit
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1992 , # 3 p. 347 - 354
