Coe, Jotham W.; Bianco, Krista E.; Boscoe, Brian P.; Brooks, Paige R.; Cox, Eric D.; Vetelino, Michael G.
Journal of Organic Chemistry, 2003 , vol. 68, # 26 p. 9964 - 9970
1: pyridine / CH2Cl2 / -78 - 20 °C
2: 87 percent / DBU / dimethylformamide / 3 h / 90 °C
View Scheme
参考文献
Coe, Jotham W.; Bianco, Krista E.; Boscoe, Brian P.; Brooks, Paige R.; Cox, Eric D.; Vetelino, Michael G.
Journal of Organic Chemistry, 2003 , vol. 68, # 26 p. 9964 - 9970
[RhCl(C8H14)]2; sodium acetate; tris-(o-tolyl)phosphine; silver perchlorate in dichloromethane
T=20°C; 48 h; Title compound not separated from byproducts;
1.1: carbonyl diimidazole / CH2Cl2 / 0.75 h
1.2: CH2Cl2
2.1: n-BuLi / tetrahydrofuran; hexane / 0.17 h / -78 °C
2.2: tetrahydrofuran; hexane / -78 - 20 °C
3.1: BCl3 / CH2Cl2 / -78 - 20 °C
View Scheme
参考文献
Coe, Jotham W.; Bianco, Krista E.; Boscoe, Brian P.; Brooks, Paige R.; Cox, Eric D.; Vetelino, Michael G.
Journal of Organic Chemistry, 2003 , vol. 68, # 26 p. 9964 - 9970
1.1: n-BuLi / tetrahydrofuran; hexane / 0.17 h / -78 °C
1.2: tetrahydrofuran; hexane / -78 - 20 °C
2.1: BCl3 / CH2Cl2 / -78 - 20 °C
View Scheme
参考文献
Coe, Jotham W.; Bianco, Krista E.; Boscoe, Brian P.; Brooks, Paige R.; Cox, Eric D.; Vetelino, Michael G.
Journal of Organic Chemistry, 2003 , vol. 68, # 26 p. 9964 - 9970
