反式-1，2二苯乙烯-D2合成路线 （共 7 条）
反应条件
hexamethyl-silane; water-d2; triphenylphosphine; bis(η3-allyl-μ-chloropalladium(II)) in various solvent(s)
T=80°C; 24 h;
参考文献
Shirakawa, Eiji; Otsuka, Hidehito; Hayashi, Tamio
Chemical Communications, 2005 , # 47 p. 5885 - 5886
反应条件
methanol-d4; hydrogen; [{IrCl(H)(BINAP)}2(μ-Cl)(μ-OMe)2]Cl in toluene
T=80°C; Catalytic hydrogenation; 18 h;
参考文献
Tani, Kazuhide; Iseki, Aika; Yamagata, Tsuneaki
Chemical Communications, 1999 , # 18 p. 1821 - 1822
反应条件
RuHCl(CO)(PPh3)3; water-d2 in 1,4-dioxane
T=100°C; 4.5 h;
参考文献
Tse, Sunny Kai San; Xue, Peng; Lin, Zhenyang; Jia, Guochen
Advanced Synthesis and Catalysis, 2010 , vol. 352, # 9 p. 1512 - 1522
反应条件
RuHCl(CO)(PPh3)3; water-d2 in 1,4-dioxane
T=100°C; 4.5 h;
参考文献
Tse, Sunny Kai San; Xue, Peng; Lin, Zhenyang; Jia, Guochen
Advanced Synthesis and Catalysis, 2010 , vol. 352, # 9 p. 1512 - 1522
反应条件
potassium phosphate; [Rh(μ-OAc)(COD)]2; diisopropylamine; cyclooctadiene in toluene
T=100°C; 48 h; Inert atmosphere; regioselective reaction;
参考文献
Yu, Jung-Yi; Shimizu, Ryosuke; Kuwano, Ryoichi
Angewandte Chemie - International Edition, 2010 , vol. 49, # 36 p. 6396 - 6399
反应条件
iodine in toluene
Heating;
参考文献
Saltiel, Jack; Waller, Andrew S.; Sears, Donald F.; Garrett, Christopher Z.
Journal of Physical Chemistry, 1993 , vol. 97, # 11 p. 2516 - 2522
反应条件
dihydridotetrakis(triphenylphosphine)ruthenium(II); perdeuterated formic acid; hydrogen in N,N-dimethyl-formamide
P=750.075 Torr; optical yield given as percent destereoselective reaction;
参考文献
Belger, Christian; Neisius, N. Matthias; Plietker, Bernd
Chemistry - A European Journal, 2010 , vol. 16, # 40 p. 12214 - 12220
