1: (+/-)-1-cyano-1,2,3,4-tetrahydronaphthalen-1-yl acetoxyacetate With immobilized Candida antarctica lipase A; water in tetrahydrofuran T=40°C; 168 h; Enzymatic reaction; 2: chloro-trimethyl-silane With pyridine in dichloromethane T=20°C; 6 h; optical yield given as percent eeenantioselective reaction;
Rh2(OAc)4(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) in dichloromethane T=40°C; 72 h;
参考文献
Coelho, Jaime A. S.; Trindade, Alexandre F.; Wanke, Riccardo; Rocha, Bruno G. M.; Veiros, Luis F.; Gois, Pedro M. P.; Pombeiro, Armando J. L.; Afonso, Carlos A. M.
European Journal of Organic Chemistry, 2013 , # 8 p. 1471 - 1478
