2,6-二甲氧基-1,4-苯醌合成路线 （共 108 条）
反应条件
acetic acid T=100°C;
参考文献
Fieser; Oxford
Journal of the American Chemical Society, 1942 , vol. 64, p. 2063
Full Text Show Details
Oxford
Journal of the Chemical Society, 1942 , p. 577
反应条件
1: 75 percent / Br2 / CHCl3 / 5 h / Ambient temperature 2: 41 percent / MeONa / 1.) r.t., 3 h, 2.) 60 deg C, 30 min View Scheme
参考文献
Bock, Hans; Nick, Sabine; Seitz, Wolfgang; Naether, Christian; Bats, Jan W.
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 1996 , vol. 51, # 2 p. 153 - 171
反应条件
1: sodium dithionite 2: 100 mg / K2CO3 / acetone / 3 h / Heating View Scheme
参考文献
Parmar; Gupta; Bisht; Mukherjee; Boll; Errington
Acta chemica Scandinavica (Copenhagen, Denmark : 1989), 1996 , vol. 50, # 6 p. 558 - 560
反应条件
hydrogen; nickel in methanol T=20°C;
参考文献
Tsukayama, Masao; Kawamura, Yasuhiko; Ishizuka, Takaaki; Hayashi, Shinji; Torii, Fumihito
Heterocycles, 2003 , vol. 60, # 12 p. 2775 - 2784
反应条件
sodium hydroxide; sodium metasilicate; diethylenetriamine-N,N,N',N'',N''-pentaacetic acid; dihydrogen peroxide in water T=25°C; 1 h; pH 9.0; Mechanism;
参考文献
Gellerstedt, Goeran; Hardell, Hanne-Lise; Lindfors, Eva-Lisa
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1980 , vol. 34, # 9 p. 669 - 674
反应条件
1: 96 percent / H2 / Raney Ni / methanol / 20 °C
2: 84 percent / K2CO3 / acetone / 0.08 h / 73 °C / microwave irradiation
3: 3.66 g / AlCl3 / diethyl ether / 1.5 h / 0 °C
4: 2.85 g / AlCl3 / acetonitrile / 1 h / 70 °C
5: 59 percent / aq. NaOH; aq. H2O2 / methanol / 2 h / 3 - 20 °C
6: 7.52 g / K2CO3 / acetone / 1.5 h / 60 °C
7: 75 percent / In(CF3SO3)3 / 0.25 h / microwave irradiation
View Scheme
参考文献
Tsukayama, Masao; Kawamura, Yasuhiko; Ishizuka, Takaaki; Hayashi, Shinji; Torii, Fumihito
Heterocycles, 2003 , vol. 60, # 12 p. 2775 - 2784
反应条件
1: 96 percent / H2 / Raney Ni / methanol / 20 °C
2: 84 percent / K2CO3 / acetone / 0.08 h / 73 °C / microwave irradiation
3: 6 percent / In(CF3SO3)3 / 0.1 h / 75 - 90 °C / microwave irradiation
View Scheme
参考文献
Tsukayama, Masao; Kawamura, Yasuhiko; Ishizuka, Takaaki; Hayashi, Shinji; Torii, Fumihito
Heterocycles, 2003 , vol. 60, # 12 p. 2775 - 2784
反应条件
1: sodium acetate; zinc-powder
2: nitrobenzene; AlCl3
View Scheme
参考文献
TWINCORE GMBH; CNRS; UNIVERSITÉ DE STRASBOURG; PIETSCHMANN, Thomas; HAID, Sibylle; GENTZSCH, Juliane; GRETHE, Christina; DAVIOUD-CHARVET, Elisabeth; LANFRANCHI, Don Antoine; ELHABIRI, Mourad; BENLLOCH-MARTIN, Xavier
Patent: WO2013/139487 A1, 2013 ;
反应条件
1: 96 percent / H2 / Raney Ni / methanol / 20 °C
2: 84 percent / K2CO3 / acetone / 0.08 h / 73 °C / microwave irradiation
3: 3.66 g / AlCl3 / diethyl ether / 1.5 h / 0 °C
4: 2.85 g / AlCl3 / acetonitrile / 1 h / 70 °C
View Scheme
参考文献
Tsukayama, Masao; Kawamura, Yasuhiko; Ishizuka, Takaaki; Hayashi, Shinji; Torii, Fumihito
Heterocycles, 2003 , vol. 60, # 12 p. 2775 - 2784
反应条件
1: 96 percent / H2 / Raney Ni / methanol / 20 °C
2: 84 percent / K2CO3 / acetone / 0.08 h / 73 °C / microwave irradiation
3: 3.66 g / AlCl3 / diethyl ether / 1.5 h / 0 °C
View Scheme
参考文献
Kuroda
Journal of the Chemical Society, 1930 , p. 767
Chem. Zentralbl., 1929 , vol. 100, # II p. 432
