3-乙氧基-2-环己烯-1-酮合成路线 （共 132 条）
反应条件
lithium in tetrahydrofuran
参考文献
Mori; Uchida; Matsui
Tetrahedron, 1977 , vol. 33, # 4 p. 385 - 387
反应条件
1: tetrahydrofuran
2: LiAlH4 / tetrahydrofuran
3: NaH / tetrahydrofuran
4: NaH; NaHCO3 / decahydronaphthalene / Heating
5: 65 percent / sodium chlorite; sodium phosphate
View Scheme
参考文献
Xiang, Min Amy; Chen, Robert H.; Demarest, Keith T.; Gunnet, Joseph; Look, Richard; Hageman, William; Murray, William V.; Combs, Donald W.; Patel, Mona
Bioorganic and Medicinal Chemistry Letters, 2004 , vol. 14, # 11 p. 2987 - 2989
反应条件
1: diethyl ether / -40 °C / Destillation des nach der Hydrolyse erhaltenen Reaktionsprodukts mit Wasser-Dampf
2: ethanol; platinum / Hydrogenation
View Scheme
参考文献
Woods et al.
Journal of the American Chemical Society, 1949 , vol. 71, p. 2028
反应条件
in tetrahydrofuran
T=0°C; 3.5 h; Inert atmosphereReflux;
参考文献
Niu, Guang-Hao; Hou, Chieh-Shen; Chuang, Gary Jing; Wu, Chi-Phi; Liao, Chun-Chen
European Journal of Organic Chemistry, 2014 , vol. 2014, # 18 p. 3794 - 3801
反应条件
tetrahydrofuran; vinyl-magnesium bromide
anschl. mit wss. HCl;
参考文献
Nasarow et al.
Doklady Akademii Nauk SSSR, 1957 , vol. 112, p. 1067,1070
Doklady Chemistry, 112-117 <1957> 167, 170
反应条件
1: LDA / -78 °C
2: LiAlH4
View Scheme
参考文献
Cossy, Janine; Furet, Nathalie; BouzBouz, Samir
Tetrahedron, 1995 , vol. 51, # 43 p. 11751 - 11764
反应条件
1: 5-Bromo-2-methyl-pent-2-ene With magnesium in diethyl ether
T=20°C;
2: 3-ethoxy-2-cyclohexen-1-one in tetrahydrofuran; diethyl ether
T=0 - 20°C;
参考文献
Palais, Laetitia; Alexakis, Alexandre
Chemistry - A European Journal, 2009 , vol. 15, # 40 p. 10473 - 10485
反应条件
in diethyl ether
1.3 h; Heating;
参考文献
Guevel, Alyx-Caroline; Hart, David J.
Journal of Organic Chemistry, 1996 , vol. 61, # 2 p. 473 - 479
反应条件
magnesium
1 h; Ambient temperature;
参考文献
Hagiwara, Hisahiro; Uda, Hisashi
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , p. 91 - 94
反应条件
tert.-butyl lithium
1) ether, pentane, -23 deg C, 2 h; 2) ether, pentane, -78 deg C, 50 min; Multistep reaction. Yields of byproduct given;
参考文献
Coates, Robert M.; Jin, Alan Qingwu
Journal of Organic Chemistry, 1997 , vol. 62, # 21 p. 7475 - 7478
