1: With [(pentamethylcyclopentadienyl)RuCl2(PPh3)]; magnesium in toluene T=60°C; 6 h; 2: in tetrahydrofuran; toluene T=25°C; 1 h; optical yield given as percent de;
参考文献
Thommes, Katrin; Kiefer, Gregor; Scopelliti, Rosario; Severin, Kay
Angewandte Chemie - International Edition, 2009 , vol. 48, # 43 p. 8115 - 8119
1: (2R,3R)-2-benzylamino-3-(4-methylsulfonylphenyl)-propane-1,3-diol With hydrogenchloride; hydrogen; palladium on activated charcoal in ethanol T=20°C; 2 h; 2: dichloroacetic acid ethyl ester With triethylamine in methanol T=30°C; 6 h; Further stages.;
