1: phenylacetylene With methyl α-D-glucopyranoside-based reagent; zinc trifluoromethanesulfonate; triethylamine in toluene
T=23°C; 0.25 h;
2: heptanal in toluene
T=40°C; 21 h; Title compound not separated from byproducts;
参考文献
Emmerson, Daniel P. G.; Hems, William P.; Davis, Benjamin G.
Organic Letters, 2006 , vol. 8, # 2 p. 207 - 210
1: With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diethylamine in N,N-dimethyl-formamide
T=20°C; Sonogashira coupling; Inert atmosphere;
2: With sodium hydroxide in N,N-dimethyl-formamide
T=140°C;
3: With palladium 10 on activated carbon in N,N-dimethyl-formamide
T=140°C;
参考文献
Sanz, Roberto; Guilarte, Veronica; Perez, Antonio
Tetrahedron Letters, 2009 , vol. 50, # 31 p. 4423 - 4426
