in melt
byproducts: H2; mixing NaNH2 and Ca(HCO2)2 before melt or addn. of Ca(HCO2)2 to molten NaNH2; exothermic reaction at melting point;; H2O unsoluble residue is CaCO3; H2O soluble part contains Na2CN2, dicyan diamide and cyanide;;
参考文献
Freidlin, L. G.; Lebedeva, A. I.
Doklady Akademii Nauk SSSR, 1938 , vol. 19, p. 701 - 705
Full Text Show Details
Gmelin Handbook: Ca: MVol.B3, 145, page 978 - 980
in neat (no solvent)
heating in autoclave under pressure above 60°C;;
参考文献
Barsky, G.; Buchanan, G. H.
Journal of the American Chemical Society, 1931 , vol. 53, p. 1270 - 1276
Full Text View citing articles Show Details
Gmelin Handbook: Ca: MVol.B1, 73, page 165 - 167