Ca-solvent slurry obtained from Ca metal evaporated at 900 deg C in tetrahydrofuran T=50°C; 2 h; Effect of solvent on the product yield and distribution is studied for THF, hexane, DME and benzene as solvents. Effect of added radical scavenger -cumene- is also studied.; Product distribution;
参考文献
Journal of Organometallic Chemistry, , vol. 332, p. 247 - 252
in tetrahydrofuran; diethyl ether addn. of Me3SnK in THF/ether to a soln. of 2-bromooctane in THF/ether at 0°C under Ar; quenching after 1 h with a large excess H2O2, extg. (pentane), washing of extracts (H2O), drying (Na2SO4), GLPC;
参考文献
Journal of the American Chemical Society, , vol. 107, # 2 p. 416 - 423
