54509-73-8合成路线 （共 3623 条）
反应条件
1: ethyl magnesium chloride With titanium(IV) isopropylate in diethyl ether
T=-78°C; 1.5 h;
2: benzoic acid methyl ester; ethene in diethyl ether
T=25°C; P=2068.65 Torr; 2 h; Further stages.;
参考文献
Eisch, John J.; Adeosun, Adetenu A.; Gitua, John N.
European Journal of Organic Chemistry, 2003 , # 24 p. 4721 - 4727
反应条件
1: With titanium(IV) isopropylate in diethyl ether
T=-78°C; P=2068.65 Torr; 0.5 h;
2: With isopropylmagnesium chloride in diethyl ether
T=-78°C; 0.5 h; Further stages.;
参考文献
Eisch, John J.; Adeosun, Adetenu A.; Gitua, John N.
European Journal of Organic Chemistry, 2003 , # 24 p. 4721 - 4727
反应条件
in tetrahydrofuran
also 1-phenylethyllithium; alkylbenzenes as reaction partners;
参考文献
Maercker, Adalbert; Stoetzel, Reinhard
Journal of Organometallic Chemistry, 1983 , vol. 254, # 1 p. 1 - 12
反应条件
(SPY-5-31)-dichloro-(κ2(C,O)-(2-isopropyloxybenzylidene))(1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene)ruthenium; [(t-Bu3P)PdBr]2 in toluene
T=100°C; P=750.075 Torr; 12 h; Autoclave;
参考文献
Baader, Sabrina; Ohlmann, Dominik M.; Goossen, Lukas J.
Chemistry - A European Journal, 2013 , vol. 19, # 30 p. 9807 - 9810
反应条件
dichloro bis(acetonitrile) palladium(II); triethylamine in tetrahydrofuran
multistep reaction: 1.) -78 deg C, 2.) -60 deg C -> room temperature; palladium-assisted alkylation of various olefin with carbanions accompanied by reductive or β-elimination isolation procedure; stereo- and regioselectivity; Product distribution;
参考文献
Hegedus,L.S.; Williams,R.E.; Mcguire,M.A.
Journal of the American Chemical Society, 1980 , vol. 102, p. 4973
反应条件
dichloro bis(acetonitrile) palladium(II); triethylamine
1.) THF, -78 deg C, 2.) -60 deg C -> room temperature; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Hegedus,L.S.; Williams,R.E.; Mcguire,M.A.
Journal of the American Chemical Society, 1980 , vol. 102, p. 4973
反应条件
dibenzoyl peroxide
T=95°C; P=2625.2 Torr;
参考文献
Morel,D.; Dawans,D.
Tetrahedron, 1977 , vol. 33, p. 1445 - 1447
反应条件
RhC((2)H)2+
in gas phase; Product distribution;
参考文献
Jacobson, D. B.; Freiser, B. S.
Journal of the American Chemical Society, 1985 , vol. 107, # 21 p. 5876 - 5883
反应条件
(i) Hg(OAc)2, (ii) NaOH; Multistep reaction;
参考文献
Hayashi,Y. et al.
Tetrahedron, 1977 , vol. 33, p. 2513 - 2519
反应条件
di-tert-butyl peroxide
T=140°C; P=30400 - 34200 Torr; 4 h; autoclave; Further byproducts given;
参考文献
Safiev, O. G.; Zorin, V. V.; Imashev, U. B.; Zlotskii, S. S.; Terent'ev, A. B.; Rakhmankulov, D. L.
Journal of Organic Chemistry USSR (English Translation), 1980 , vol. 16, # 7 p. 1192 - 1195
Zhurnal Organicheskoi Khimii, 1980 , vol. 16, # 7 p. 1388 - 1392
