反应条件
in ethanol; dichloromethane Addn. of a NaBH4 soln. (EtOH) to a stirred soln. of Mn-complex in CH2Cl2 under N2, stirring (1.5 h), colour turns from deep blue to bright red.; Evapn. of solvent in vac., pumping for 1 h to eleminate the free phosphine, extg. of red solid (hexane), filtn., addn. of EtOH, slow evapn. in vac., elem. anal.;
参考文献
Miguel, Daniel; Riera, Victor; Miguel, Jesus A.; Diego, Fernando; Bois, Claudette; Jeannin, Yves
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1990 , p. 2719 - 2728
