3,3-二甲基-1-丁烯合成路线 （共 347 条）
反应条件
C18H32ClIrOP2S; sodium t-butanolate T=200°C; 15 h; Inert atmosphereSchlenk techniqueGloveboxSealed tube; Reagent/catalystConcentrationTime;
参考文献
Yao, Wubing; Zhang, Yuxuan; Jia, Xiangqing; Huang, Zheng
Angewandte Chemie - International Edition, 2014 , vol. 53, # 5 p. 1390 - 1394
Angew. Chem., 2014 , vol. 126, # 5 p. 1414 - 1418
反应条件
aluminum oxide; {4-OK-C6H2-2,6-[OP(t-Bu)2]2}Ir(C2H4) 39.9667 h; Heating; Product distribution / selectivity;
参考文献
THE UNIVERSITY OF NORTH CAROLINA AT CHAPEL HILL
Patent: WO2008/153869 A2, 2008 ;
Location in patent: Page/Page column 19-20 ;
反应条件
hydrogen; silica gel; ruthenium in gas T=200°C; 0.0833333 h; var. temp., var. contact time; Product distributionMechanism;
参考文献
Toyir, Jamil; Leconte, Michel; Niccolai, Gerald P.; Basset, Jean-Marie
Journal of Catalysis, 1995 , vol. 152, # 2 p. 306 - 312
反应条件
deuterium; silica gel; nickel T=-19.1°C; P=20.3 Torr; other silica-supported metal-catalysts; Product distributionMechanism;
参考文献
Brown, Ronald; Kemball, Charles
Journal of the Chemical Society, Faraday Transactions, 1993 , vol. 89, # 14 p. 2519 - 2526
反应条件
(κ3-C6H3-2,6-[CH2P(i-C3H7)2]2)IrH4; tricyclo[3.3.1.1{3,7}]decane; Cp*TaCl2(C2H4) in n-heptane T=100°C; 18 h; Inert atmosphere; Catalytic behavior;
参考文献
Leitch, David C.; Lam, Yan Choi; Labinger, Jay A.; Bercaw, John E.
Journal of the American Chemical Society, 2013 , vol. 135, # 28 p. 10302 - 10305
反应条件
(iPr3P)2IrH5 T=150°C; 120 h; reaction time; other catalysts: <(p-F-C6H4)3P>2IrH5, <(p-F-C6H4)3P>3RuH4, (Me3P)2IrH5, (Ph3P)3RuH4, (Ar3P)2ReH7; Product distributionMechanism;
参考文献
Felkin, Hugh; Fillebeen-Khan, Tauqir; Gault, Yvonne; Holmes-Smith, Rupert; Zakrzewski, Janusz
Tetrahedron Letters, 1984 , vol. 25, # 12 p. 1279 - 1282
反应条件
aluminum oxide; C24H42IrO3P2(1-)*K(1+) T=200°C; 40 h; Inert atmosphere; Kinetics; Reagent/catalystTemperatureTime;
参考文献
Huang, Zheng; Brookhart, Maurice; Goldman, Alan S.; Kundu, Sabuj; Ray, Amlan; Scott, Susannah L.; Vicente, Brian C.
Advanced Synthesis and Catalysis, 2009 , vol. 351, # 1-2 p. 188 - 206
反应条件
rhenium bis triphenylphosphine heptahydride; phosphorous acid trimethyl ester 1.) 70 deg C, 40 min; 2.) 60 deg C, 1 h; other objects: selectivity; n-alkanes: n-heptane, n-octane; Product distributionMechanism;
参考文献
Baudry, Denise; Ephritikhine, Michel; Felkin, Hugh; Zakrzewski, Janusz
Tetrahedron Letters, 1984 , vol. 25, # 12 p. 1283 - 1286
反应条件
potassium tert-butylate T=-20°C; 36 h; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Apeloig; Karni; Stang; Fox
Journal of the American Chemical Society, 1983 , vol. 105, # 14 p. 4781 - 4792
反应条件
potassium tert-butylate T=-20°C; 36 h; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Apeloig; Karni; Stang; Fox
Journal of the American Chemical Society, 1983 , vol. 105, # 14 p. 4781 - 4792
