3,3-二甲基-1-丁烯合成路线 （共 347 条）
反应条件
C18H32ClIrOP2S; sodium t-butanolate in para-xylene T=150°C; 12 h; Inert atmosphereSchlenk techniqueGloveboxSealed tube;
参考文献
Angewandte Chemie - International Edition, , vol. 53, # 5 p. 1390 - 1394
Angew. Chem., , vol. 126, # 5 p. 1414 - 1418
反应条件
hydrogen; silica gel; ruthenium in gas T=200°C; 0.0833333 h; var. temp., var. contact time; Product distributionMechanism;
参考文献
Journal of Catalysis, , vol. 152, # 2 p. 306 - 312
反应条件
anhydrous aluminium sulphate T=275°C;
参考文献
Shell Devel. Co.
Patent: US2217252 , 1938 ;
参考文献
Sen, Ayusman; Lai, Ta-Wang
Journal of the American Chemical Society, 1981 , vol. 103, # 15 p. 4627 - 4629
反应条件
aluminum oxide; {4-OK-C6H2-2,6-[OP(t-Bu)2]2}Ir(C2H4) 39.9667 h; Heating; Product distribution / selectivity;
参考文献
THE UNIVERSITY OF NORTH CAROLINA AT CHAPEL HILL
Patent: WO2008/153869 A2, 2008 ;
Location in patent: Page/Page column 19-20 ;
反应条件
aluminum oxide; C24H42IrO3P2(1-)*K(1+) T=200°C; 40 h; Inert atmosphere; Kinetics; Reagent/catalystTemperatureTime;
参考文献
Huang, Zheng; Brookhart, Maurice; Goldman, Alan S.; Kundu, Sabuj; Ray, Amlan; Scott, Susannah L.; Vicente, Brian C.
Advanced Synthesis and Catalysis, 2009 , vol. 351, # 1-2 p. 188 - 206
反应条件
T=400°C; Isomerisierung und Fragmentierung; Produkt5: Propen;
参考文献
Obolenzew; Grjasew
Zhurnal Obshchei Khimii, 1951 , vol. 21, p. 1588,1594,1596;engl.Ausg.S.1741
反应条件
IrH2{C6H3-2,6-(CH2PBu(t)2)2}; Mo(N-2,6-i-Pr2C6H3)(C3H6)(pyr)(2,6-bis(2,4,6-triisopropylphenyl)phenol) T=180°C; Cross Metathesis; 24 h; Schlenk technique;
参考文献
Dobereiner, Graham E.; Yuan, Jian; Schrock, Richard R.; Goldman, Alan S.; Hackenberg, Jason D.
Journal of the American Chemical Society, 2013 , vol. 135, # 34 p. 12572 - 12575
反应条件
hydrogen; silica gel; rhodium Product distributionMechanism;
参考文献
Leconte, M.; Theolier, A.; Rojas, D.; Basset, J. M.
Journal of the American Chemical Society, 1984 , vol. 106, # 4 p. 1141 - 1142
反应条件
potassium hydrogencarbonate in water; N,N-dimethyl-formamide T=-10 - 20°C; 2 h; Inert atmosphere; regioselective reaction;
参考文献
Girardin, Melina; Alsabeh, Pamela G.; Lauzon, Sophie; Dolman, Sarah J.; Ouellet, Stephane G.; Hughes, Greg
Organic Letters, 2009 , vol. 11, # 5 p. 1159 - 1162
