3,3-二甲基-1-丁烯合成路线 （共 347 条）
反应条件
aluminum oxide; aluminium trichloride T=180°C; P=18387.7 Torr;
反应条件
in toluene 3-tert-butyltitanacyclobutane and diphenylketene in toluene is heated at 80°C for 10 min, solids pptd.; solution removed, solid is washed (pentane, ether), dried overnight, recrystn. (ether, CH2Cl2 or toluene); elem. anal.;
参考文献
Ho, Suzzy C.; Hentges, S.; Grubbs, Robert H.
Organometallics, 1988 , vol. 7, p. 780 - 782
反应条件
cocatalyst: AlCl3 in benzene 1-2 h; filtered, investigated by NMR;
参考文献
Journal of the American Chemical Society, , vol. 102, p. 4515
反应条件
organometallic tantalum hydride grafted onto silica T=150°C; P=750.075 Torr; 5 - 8.33333 h; Product distribution / selectivity;
参考文献
EP1932820 A1, ;
Page/Page column 15 ;
反应条件
W(H)3/Al2O3 T=150°C; P=750.075 Torr; 16 h;
参考文献
Chemical Communications, , # 18 p. 2523 - 2525
反应条件
sodium tetrahydroborate in dimethyl sulfoxide; benzene Irradiation (UV/VIS); mixt. of substrate and mercurial is irradiated in nitrogen-purged solvent in Pyrex tube with 275-W sunlamp for 2 h; mixt. is worked up with NaBH4, (1)H-NMR;
参考文献
Organometallics, , vol. 7, p. 696 - 702
反应条件
Ta(CHCMe3)(OCMe3)2(PMe3)Cl in benzene T=25°C; 2 h; other reagents, time; Product distribution;
参考文献
Journal of the American Chemical Society, , vol. 103, p. 1440
反应条件
T=25°C; P=499.54 Torr;
参考文献
Chemistry - A European Journal, , vol. 9, # 4 p. 971 - 975
反应条件
in benzene-d6 equilibrium react.;
参考文献
Journal of the American Chemical Society, , vol. 110, p. 4964
反应条件
in pentane 2 equiv. of vinyltrimethylsilane in pentane at 25°C for 10 min;;
参考文献
Schaverien, Colin J.; Dewan, John C.; Schrock, Richard R.
Journal of the American Chemical Society, 1986 , vol. 108, # 10 p. 2771 - 2773
