3,3-二甲基-1-丁烯合成路线 （共 347 条）
反应条件
3-methyl-2-amino-pyridine; Wilkinson's catalyst; water; cyclohexylamine; benzoic acid in toluene
T=130°C; 0.75 h;
参考文献
Lee, Dong Hun; Jo, Eun-Ae; Park, Jung-Woo; Jun, Chul-Ho
Tetrahedron Letters, 2010 , vol. 51, # 1 p. 160 - 163
反应条件
1: With 3-methyl-2-amino-pyridine; Wilkinson's catalyst; α,α,α-Trifluoro-p-toluic acid; cyclohexylamine in toluene
T=130°C; 12 h;
2: With hydrogenchloride; water in tetrahydrofuran
参考文献
Cha, Kyung-Mi; Lee, Hyejeong; Park, Jung-Woo; Lee, Yura; Jo, Eun-Ae; Jun, Chul-Ho
Chemistry - An Asian Journal, 2011 , vol. 6, # 8 p. 1926 - 1930
反应条件
3-methyl-2-amino-pyridine; Wilkinson's catalyst; 1-Hexylamine; α,α,α-Trifluoro-p-toluic acid; water in toluene
T=150°C; 24 h;
参考文献
Cha, Kyung-Mi; Jo, Eun-Ae; Jun, Chul-Ho
Synlett, 2009 , # 18 p. 2939 - 2942
反应条件
3-methyl-2-amino-pyridine; Wilkinson's catalyst
T=150°C; 48 h;
参考文献
Jun, Chul-Ho; Lee, Hyuk
Journal of the American Chemical Society, 1999 , vol. 121, # 4 p. 880 - 881
反应条件
1: CH2Cl2 / 0.33 h / -10 - 20 °C
2: 86 percent / CH2Cl2 / 20 °C
3: 81 percent / Na2CO3; MCPBA / CH2Cl2 / 5 h / 20 °C
View Scheme
参考文献
Temmem; Uguen; De Cian; Gruber
Tetrahedron Letters, 2002 , vol. 43, # 17 p. 3175 - 3179
反应条件
neopentane2,2-dimethylpropane in dichloromethane
T=14 - 15°C; 1.5 h; Irradiation; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Tlumak, Robert L.; Day, James C.; Slanga, Joseph P.; Skell, Philip S.
Journal of the American Chemical Society, 1982 , vol. 104, # 25 p. 7257 - 7267
反应条件
1: dibenzoyl peroxide; sulfuryl chloride
2: ethanolic KOH-solution
View Scheme
参考文献
Ecke et al.
Journal of the American Chemical Society, 1950 , vol. 72, p. 1511
反应条件
triphenyl phosphite; hydrogen; [rhodium(I)(carbonyl)2(acetylacetonate)]
1.) benzene, 60 degC, 50-100 atm; Yield given. Multistep reaction;
参考文献
Nozaki, Kyoko; Nanno, Tetsuo; Takaya, Hidemasa
Journal of Organometallic Chemistry, 1997 , vol. 527, # 1-2 p. 103 - 108
反应条件
1: bromine / unter Lichtausschluss
2: sodium amide; liquid ammonia
3: aq.-ethanolic HCl
View Scheme
参考文献
Puterbaugh; Newman
Journal of the American Chemical Society, 1957 , vol. 79, p. 3469
反应条件
di-tert-butyl peroxide
T=140 - 150°C; 3.5 h;
参考文献
Abramovici,M.; Pines,H.
Journal of Organic Chemistry, 1969 , vol. 34, p. 266 - 270
