3,3-二甲基-1-丁烯合成路线 （共 347 条）
反应条件
hydrogen; silica gel; rhodium
Product distributionMechanism;
参考文献
Leconte, M.; Theolier, A.; Rojas, D.; Basset, J. M.
Journal of the American Chemical Society, 1984 , vol. 106, # 4 p. 1141 - 1142
反应条件
C18H32ClIrOP2S; sodium t-butanolate
T=200°C; 1 h; Inert atmosphereSchlenk techniqueGloveboxSealed tube; Reagent/catalystConcentrationTime;
参考文献
Yao, Wubing; Zhang, Yuxuan; Jia, Xiangqing; Huang, Zheng
Angewandte Chemie - International Edition, 2014 , vol. 53, # 5 p. 1390 - 1394
Angew. Chem., 2014 , vol. 126, # 5 p. 1414 - 1418
反应条件
di-tert-butyl peroxide; hypophosphorous ether
T=135°C; 22 h; Buchi reactor;
参考文献
ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE (EPFL)
Patent: US2012/10411 A1, 2012 ;
Location in patent: Page/Page column 12-13 ;
参考文献
UNIVERSITÄT ULM; ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE (EPFL)
Patent: US2011/265876 A1, 2011 ;
反应条件
sodium hydroxide; sodium tetrahydroborate; mercury(II) diacetate
other alcohols and mercuric salts; Product distribution;
参考文献
Brown, Herbert C.; Kurek, Joseph T.; Rei, Min-Hon; Thompson, Kerry L.
Journal of Organic Chemistry, 1984 , vol. 49, # 14 p. 2551 - 2557
反应条件
1.) benzene, room temp., 1 h, 2.) room temp., 15 h; Yield given. Multistep reaction;
参考文献
Toshimitsu, Akio; Uemura, Sakae; Okano, Masaya; Watanabe, Nanao
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5246 - 5251
反应条件
1: 1.) benzene, room temp., 1 h, 2.) room temp., 15 h
2: 1.) ozone / 1.) dichloromethane, -78 deg C, 0.5 h, 2.) carbon tetrachloride, reflux, 0.16 h
View Scheme
参考文献
Toshimitsu, Akio; Uemura, Sakae; Okano, Masaya; Watanabe, Nanao
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5246 - 5251
反应条件
di-tert-butyl peroxide
T=140 - 150°C; 3.5 h;
参考文献
Abramovici,M.; Pines,H.
Journal of Organic Chemistry, 1969 , vol. 34, p. 266 - 270
反应条件
hydrogen; silica gel; rhodium
Product distributionMechanism;
参考文献
Leconte, M.; Theolier, A.; Rojas, D.; Basset, J. M.
Journal of the American Chemical Society, 1984 , vol. 106, # 4 p. 1141 - 1142
反应条件
sodium carbonate; triethylamine; palladium dichloride; Tl(OCOCF3)3
Yield given. Multistep reaction;
参考文献
Larock, R. C.; Varaprath, S.; Lau, H. H.; Fellows, C. A.
Journal of the American Chemical Society, 1984 , vol. 106, # 18 p. 5274 - 5284
