3,3-二甲基-1-丁烯合成路线 （共 347 条）
反应条件
hydrogen; Co2Rh2(CO)12 in hexane
T=0°C; P=7500.6 Torr; 24 h; autoclave; different catalysts; investigation of low temperature H2 activation; Product distributionMechanism;
参考文献
Horvath, Istvan T.; Garland, Marc; Bor, Gyoergy; Pino, Piero
Journal of Organometallic Chemistry, 1988 , vol. 358, p. C17 - C22
反应条件
1: With [Ir(acetylacetonate)(1,5-cyclooctadiene)]; triphenylphosphine in N-methylpyrrolidone
T=20 - 100°C; P=5250.53 Torr; Inert atmosphereAutoclave;
2: With hydrogen in N-methylpyrrolidone
T=100°C; P=9750.98 Torr; 20 h; Autoclave; regioselective reaction;
参考文献
Piras, Irene; Jennerjahn, Reiko; Jackstell, Ralf; Spannenberg, Anke; Franke, Robert; Beller, Matthias
Angewandte Chemie - International Edition, 2011 , vol. 50, # 1 p. 280 - 284
反应条件
[RhCl(η2:η2-cycloocta-1,5-diene)]2; 1,3-bis-(diphenylphosphino)propane; hydrogen in water; toluene
T=120°C; P=7500.75 Torr; 20 h; Overall yield = 85 percentChromat.; regioselective reaction;
参考文献
Uhlemann, Marcus; Doerfelt, Stephan; Boerner, Armin
Tetrahedron Letters, 2013 , vol. 54, # 18 p. 2209 - 2211
反应条件
[(C5Me4CF3)Rh(C2H3SiMe3)2] in deuterated toluene
T=60°C; Formylation; Transfer formylation; 24 h;
参考文献
Lenges, Christian P.; Brookhart, Maurice
Angewandte Chemie - International Edition, 1999 , vol. 38, # 23 p. 3533 - 3537
反应条件
hydrogen; rhodium in benzene
T=80°C; P=58840.6 Torr; 3 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Gueven, Sabriye; Nieuwenhuizen, Marko M. L.; Hamers, Bart; Franke, Robert; Priske, Markus; Becker, Marc; Vogt, Dieter
ChemCatChem, 2014 , vol. 6, # 2 p. 603 - 610
反应条件
hydrogen; methanesulfonic acid; lt;Pt(C2H4)(DPPB)gt; in toluene
T=100°C; P=38000 Torr; var. olefins; Product distribution;
参考文献
Botteghi, Carlo; Paganelli, Stefano
Journal of Organometallic Chemistry, 1991 , vol. 417, # 1/2 p. C41 - C45
反应条件
dodecacarbonyltetrarhodium(0); [Re(CO)5]H; hydrogen in hexane
T=24.84°C; P=22502.3 Torr; 2 h; Autoclave; Kinetics; Reagent/catalyst; regioselective reaction;
参考文献
Li, Chuanzhao; Chen, Li; Garland, Marc
Advanced Synthesis and Catalysis, 2008 , vol. 350, # 5 p. 679 - 690
反应条件
dilithium tetrachloropalladate; potassium carbonate; triethylamine
1.) CH2Cl2, 25 deg C, 16 h; 2.) 50 deg C, 5 h; Yield given. Multistep reaction;
参考文献
Larock, R.C.; Liu, C.-L.; Lau, H. H.; Varaprath, S.
Tetrahedron Letters, 1984 , vol. 25, # 40 p. 4459 - 4462
反应条件
1: 80percent m-chloroperbenzoic acid / CH2Cl2 / 48 h / 45 °C
2: sodium hydrosulfide, carbon disulfide / methanol / 3 h / 25 - 30 °C
View Scheme
参考文献
Wu, Shao-Yong; Hirashima, Akinori; Takeya, Ryuko; Eto, Morifusa
Agricultural and Biological Chemistry, 1988 , vol. 52, # 11 p. 2911 - 2918
反应条件
in dichloromethane
T=0°C; 4 h; Irradiation;
参考文献
Akasaka, Takeshi; Furukawa, Naomichi; Oae, Shigeru
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1980 , p. 1257 - 1261
