in ethanol Sn compd. dissolved in abs. ethanol at 0°C under Ar, then added NaBH4, allowed to warm to room temp., stirred for 1 h; EtOH removed in vac., residue dissolved in hexane, washed with water, dried, evapd. under reduced pressure;
参考文献
Brunton, Shirley A.; Jones, Keith
Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 5 p. 763 - 768
in benzene soln. H3Al*NMe3 in benzene was treated dropwise with (n-Bu3Sn)2O and stirred for 16 h at room temp.; ppt. was filtered, washed with hexane and dried in vacuo;
in toluene 1:2; azeotropic dehydration; boiling for 2-4 h; removal of solvent;
参考文献
Blunden, S. J.; Chapman, A. H.; Crowe, A. J.; Smith, P. J.
Intern. Pest Control., 1978 , vol. 20, p. 12
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Gmelin Handbook: Sn: Org.Comp.12, 1.4.1.1.1.5.12, page 206 - 211
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反应条件
in toluene dropping O(SnBu3)2 in toluene to (C5Me5)TiF3 in toluene under stirring; removal of FSnBu3 by filtration after 12 h, removal of the solvent from the filtrate in vacuo and recrystn. of the residue from n-hexane, elem. anal.;
参考文献
Roesky, Herbert W.; Leichtweis, Iring; Noltemeyer, Mathias
Inorganic Chemistry, 1993 , vol. 32, p. 5102 - 5104
