in water T=25°C; electrocatalytic oxidation on gold electrodes; method: cyclic voltammetry; dependence of voltage sweep rates, pH, concentration, potential; Tafel slopes; ΔH(excit), ΔS(excit), ΔG(excit); MechanismKinetics;
参考文献
Alonso, C.; Gonzalez-Velsasco, J.
Zeitschrift fuer Physikalische Chemie (Leipzig), 1990 , vol. 271, # 4 p. 799 - 822
ammonia; hydrogen; catalyst obtained by prereduction from precursor whose catalytically active composition before the reduction with hydrogen comprised 13percent by weight of Cu, calculated as CuO, 28percent by weight of NI, calculated as NiO, 28percent by weight of Co, calculated as CoO and 31percent by weight of Zr, calculated as ZrO2 in water T=250°C; P=37503.8 - 225023 Torr; Autoclave; Product distribution / selectivity;
参考文献
BASF SE
Patent: US2010/240894 A1, 2010 ;
Location in patent: Page/Page column 12 ;