2,3-二甲基-2-丁烯合成路线 （共 833 条）
反应条件
oxirane; tert-butyl-pyrocatechol; tetraethylammonium bromide
T=155°C; 2 h;
参考文献
Mendoza, Abraham; Ishihara, Yoshihiro; Baran, Phil S.
Nature Chemistry, 2012 , vol. 4, # 1 p. 21 - 25
反应条件
1: potassium tert-butylate / hexane / 2 h / 0 °C / |Inert atmosphere
2: N,N-dimethyl-aniline / 140 °C / |Inert atmosphere
View Scheme
参考文献
Ishihara, Yoshihiro; Mendoza, Abraham; Baran, Phil S.
Tetrahedron, 2013 , vol. 69, # 27-28 p. 5685 - 5701
反应条件
1: 36.5 percent / N-bromosuccinimide, benzoylperoxide / CCl4 / 70 °C
2: 43.3 percent / dimethylsulfoxide / 1.) 50 deg C, 30 min, 2.) r.t., overnight
View Scheme
参考文献
Okada, Katsuhide; Kiyooka, Fumiharu; Nakanishi, Eiji; Hirano, Masachika; Ohno, Isao; et al.
Agricultural and Biological Chemistry, 1980 , vol. 44, # 11 p. 2595 - 2600
参考文献
Kondakow
Journal fuer Praktische Chemie (Leipzig), 1893 , vol. <2>48, p. 485
反应条件
boron trifluoride
T=75°C; P=441305 Torr;
参考文献
Malachowski; Jurkiewicz
Roczniki Chemii, 1950 , vol. 24, p. 88,107
Chem.Abstr., 1954 , p. 3914
反应条件
N-bromosuccinmide; dibenzoyl peroxide in tetrachloromethane
3 h; Heating;
参考文献
Clennan, Edward L.; Chen, Xiangning
Journal of the American Chemical Society, 1989 , vol. 111, # 15 p. 5787 - 5792
反应条件
in tetrachloromethane
byproducts: succinimide; Irradiation (UV/VIS); A mixt. of dimethylbutene, N-bromosuccinimide and CCl4 was stirred under flowing Ar at room temp for 1.5 h und refluxed under UV-irradiation for 5 h.; Succinimide was sepd. by suction filtn., CCl4 and excess alkene-compd. were removed from filtrate by distn. (reduced pressure), residue was chromd. (silica gel; pentane/ether), fractions are combined and evapd. under reduced pressure.;
参考文献
Huang, Qiurong; Gingrich, Henry L.; Jones, Maitland Jr.
Inorganic Chemistry, 1991 , vol. 30, p. 3254 - 3257
反应条件
in chloroform-d1
PhotolysisInert atmosphere; Concentration;
参考文献
Raphael Karikachery, Alice; Lee, Han Baek; Masjedi, Mehdi; Ross, Andreas; Moody, Morgan A.; Cai, Xiaochen; Chui, Megan; Hoff, Carl D.; Sharp, Paul R.
Inorganic Chemistry, 2013 , vol. 52, # 7 p. 4113 - 4119
参考文献
Wohl
Chemische Berichte, 1919 , vol. 52, p. 61
参考文献
Wickramasinghe, Lasantha A.; Sharp, Paul R.
Inorganic Chemistry, 2014 , vol. 53, # 3 p. 1430 - 1442
