1,3-二氧杂烷-2-甲醇合成路线 （共 10 条）
反应条件
hydrogen; palladium on activated charcoal in water T=160°C; P=103430 Torr; 4 h;
参考文献
Sanderson, John R.; Yeakey, Ernest L.; Lin, Jiang J.; Duranleau, Roger; Marquis, Edward T.
Journal of Organic Chemistry, 1987 , vol. 52, # 15 p. 3243 - 3246
反应条件
hydrogen; palladium(II) hydroxide/carbon in methanol
T=20°C; 15 h;
参考文献
Eisai Co., Ltd.
Patent: US2007/10542 A1, 2007 ;
Location in patent: Page/Page column 82 ;
反应条件
2-hydroxy-pyridine; hydrogen; [rhodium(I)(carbonyl)2(acetylacetonate)] in various solvent(s)
T=230°C; P=1499480 Torr; 4.5 h; Further byproducts given. Title compound not separated from byproducts;
参考文献
Fahey, Darryl R.
Journal of the American Chemical Society, 1981 , vol. 103, # 1 p. 136 - 141
反应条件
hydrogenchloride in water
T=20°C; 1 h;
参考文献
SOLVAY SOLEXIS S.p.A.; MARCHIONNI, Giuseppe; TORTELLI, Vito
Patent: WO2010/3931 A1, 2010 ;
Location in patent: Page/Page column 12 ;
反应条件
potassium hydroxide
T=160°C;
参考文献
Spaeth; Raschik
Monatshefte fuer Chemie, 1946 , vol. 76, p. 65,76
反应条件
T=285°C; Leiten ueber einen Chrom enthaltenden Kupfer-Katalysator;
参考文献
Carbide and Carbon Chem. Co.
Patent: US2140938 , 1936 ;
反应条件
sodium hydroxide in water; dimethyl sulfoxide
T=-10.1°C; ΔH0*, ΔS0*; other temp.; Rate constantThermodynamic data;
参考文献
Koole, Leo H.; Olders, Edith A. T. A.; Opresnik, Marko; Buck, Henk M.
Recueil des Travaux Chimiques des Pays-Bas, 1990 , vol. 109, # 2 p. 55 - 58
反应条件
iron (III) acetylacetonate; oxygen in water
T=150°C; 100 h; other acetloacetonates, also in basic solution; Product distribution;
参考文献
Schnurpfeil, D.; Maurer, G.
Journal fuer Praktische Chemie/Chemiker-Zeitung, 1994 , vol. 336, # 4 p. 307 - 310
反应条件
tertiary butyl peroxybenzenoate
T=100 - 130°C; 4 h; further products (2-hydroxymethoxymethyl-1,3-dioxolane and CH2O homologues) isolated; also reaction with paraformaldehyde, and other initiators investigated; Product distributionMechanism;
参考文献
Sanderson, John R.; Yeakey, Ernest L.; Lin, Jiang J.; Duranleau, Roger; Marquis, Edward T.
Journal of Organic Chemistry, 1987 , vol. 52, # 15 p. 3243 - 3246
反应条件
N,N-dimethyl-aniline in hexane
2 h; Heating;
参考文献
Koole, Leo H.; Kooyk, Raymond J. L. van; Buck, Henk M.
Journal of the American Chemical Society, 1985 , vol. 107, # 13 p. 4032 - 4037
