in water; butan-1-ol T=25°C; effect of butanol concentration; Rate constant;
参考文献
Bertoncini, Clelia R. A.; Nome, Faruk; Cerichelli, Giorgio; Bunton, Clifford A.
Journal of Physical Chemistry, 1990 , vol. 94, # 15 p. 5875 - 5878
→
反应条件
in water High Pressure; 3 equiv. of Br-compd. was added to W-compd. soln. under stirring, ppt. was filtered off, dried at room temp., further Br-compd. was added, Swagelok cell, heating at 1000 °C for 10 h; gradual cooling to room temp.;
参考文献
Shanmugam, Sangaraju; Jacob, David S.; Gedanken, Aharon
Journal of Physical Chemistry B, 2005 , vol. 109, # 41 p. 19056 - 19059
→
反应条件
in water High Pressure; 3 equiv. of Br-compd. was added to W-compd. soln. under stirring, ppt. was filtered off, dried at room temp., further Br-compd. was added, Swagelok cell, heating at 900 °C for 10 h; gradual cooling to room temp.;
参考文献
Shanmugam, Sangaraju; Jacob, David S.; Gedanken, Aharon
Journal of Physical Chemistry B, 2005 , vol. 109, # 41 p. 19056 - 19059
