(1S,2s)-反式-1,2-环己二醇合成路线 (共 85 条)
反应条件
C43H60N6O8; N-ethyl-N,N-diisopropylamine in toluene T=0°C; 48 h; Inert atmosphere; enantioselective reaction;
参考文献
Chemical Communications, , vol. 50, # 10 p. 1221 - 1223
反应条件
water Rhizopus nigricans ATCC 6227b; Yield given. Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 49, # 4 p. 675 - 679
反应条件
nickel; calcium carbonate in ethanol 3 h; Heating;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 2715 - 2720
反应条件
HEPES buffer; Nicotiana tabacum GTF-II glucosyltransferase T=35°C; pH=7.0; 36 h; Enzymatic reaction;
参考文献
Tetrahedron Asymmetry, , vol. 15, # 15 p. 2319 - 2321
反应条件
1: 1.) (COCl)2, DMSO, 2.) Et3N / 1.) CH2Cl2, -78 deg C, 45 min, 2.) -78 deg C to r.t., 12 h 2: SmI2 / tetrahydrofuran; methanol / 0.5 h / Ambient temperature View Scheme
参考文献
Journal of the Chemical Society - Perkin Transactions 1, , # 12 p. 1639 - 1645
反应条件
1: rabbit liver microsomes / H2O / 0.42 h 2: Raney nickel, calcium carbonate / ethanol / 3 h / Heating View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 2715 - 2720
反应条件
C42H60N6O7 in toluene T=20°C; 58 h;
参考文献
Journal of Organic Chemistry, , vol. 78, # 17 p. 8465 - 8484
反应条件
water T=30°C; 0.1 M phosphate buffer, pH 7, porcine liver esterase E.(1)C311; Yield given. Yields of byproduct given;
参考文献
Journal of the Chemical Society, Chemical Communications, , # 10 p. 808 - 810
反应条件
NADH-H+; endo-bicyclolt;3.2.0gt;hept-2-en-6-ol; diacetyl reductase; TEA-HCl buffer 48 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 62, # 6 p. 1854 - 1856
反应条件
silver(I) acetate; acetic acid trans-cyclohexanediol-(1.2);
参考文献
Annales de Chimie (Cachan, France), , vol. <8> 6, p. 208
Bulletin de la Societe Chimique de France, , vol. <3> 33, p. 269