2-乙酰基萘-1,4-二酮合成路线 （共 54 条）
反应条件
1: aq. NaOH solution; aqueous hydrochloric acid / anschliessendes Erwaermen mit Natriumdithionit
2: FeCl3; aqueous HCl; water / 40 - 50 °C
View Scheme
参考文献
Spruit
Recueil des Travaux Chimiques des Pays-Bas, 1947 , vol. 66, p. 655,667
参考文献
Friedlaender
Chemische Berichte, 1895 , vol. 28, p. 1947
反应条件
dipotassium peroxodisulfate; sodium dithionite; potassium carbonate; silver nitrate
Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Giles, Robin G.F.; Green, Ivan R.; Hugo, Victor I.; Mitchell, Peter R.K.; Yorke, Selwyn C.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 10 p. 2309 - 2313
反应条件
in benzene
dissolved acylquinone and allylstannane stood under Ar; concd.; column chromy. (silica gel); eluted (hexane/ether); NMR; IR; mass spectra; elem. anal.;
参考文献
Maruyama; Matano
Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 12 p. 3877 - 3885
反应条件
dipotassium peroxodisulfate; silver nitrate in water; acetonitrile
T=70°C; 2 h;
参考文献
Giles, Robin G.F.; Green, Ivan R.; Hugo, Victor I.; Mitchell, Peter R.K.; Yorke, Selwyn C.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 10 p. 2309 - 2313
反应条件
in acetonitrile
1 h; Further byproducts given;
参考文献
Maruyama; Matano
Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 12 p. 3877 - 3885
反应条件
in acetonitrile
1 h; Further byproducts given;
参考文献
Maruyama; Matano
Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 12 p. 3877 - 3885
反应条件
in benzene-d6
dissolved acylquinone and allylstannane stood for 24 h under Ar; further standing for 24 h; column chromy. (silica gel); fractions collected; concetrated; NMR;
参考文献
Maruyama; Matano
Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 12 p. 3877 - 3885
反应条件
in acetonitrile
1 h; Further byproducts given;
参考文献
Maruyama; Matano
Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 12 p. 3877 - 3885
反应条件
in benzene
21 h; Further byproducts given;
参考文献
Maruyama; Matano
Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 12 p. 3877 - 3885
