2-(叔丁基)-3,3-二甲基-1-丁烯合成路线 （共 32 条）
反应条件
pyridine; thionyl chloride
参考文献
Lomas,J.S. et al.
Tetrahedron Letters, 1971 , p. 599 - 602
反应条件
benzoic acid
1.) 48 20 deg C; 2.) 24 h, 20 deg C; Yield given. Multistep reaction;
参考文献
Cristau, Henri-Jean; Ribeill, Yves; Chiche, Laurent; Plenat, Francoise
Journal of Organometallic Chemistry, 1988 , vol. 352, p. C47 - C50
反应条件
1: sodium; pentane / <35 / und Oxidieren der bei 150-165grad siedenden Fraktion mit HNO3
3: iodine
View Scheme
参考文献
Howard et al.
Journal of Research of the National Bureau of Standards (United States), 1947 , vol. 38, p. 391
Chem. Zentralbl., 1947 , vol. 118, p. 5291
反应条件
in diphenylether
T=140°C; Ea, log10(A), ΔH(excit.), ΔS(excit.); kinetic isotope effects; KineticsThermodynamic dataMechanism;
参考文献
Lomas, John S.; Thorne, Melanie P.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1982 , p. 221 - 226
反应条件
bei der Destillation;
参考文献
Whitmore; Laughlin
Journal of the American Chemical Society, 1933 , vol. 55, p. 3736
反应条件
bei der langsamen Destillation;
参考文献
Nasarow
Chemische Berichte, 1936 , vol. 69, p. 20
Doklady Akademii Nauk SSSR, 1936 , vol. 10, p. 81
Chem. Zentralbl., 1936 , vol. 107, # II p. 59
反应条件
bei der langsamen Destillation;
参考文献
Howard et al.
Journal of Research of the National Bureau of Standards (United States), 1947 , vol. 38, p. 391
Chem. Zentralbl., 1947 , vol. 118, p. 5291
反应条件
1: 1) BH3*THF; 2) 30percent aq. H2O2, NaOH / 1) r.t., 4 h; 2) EtOH, r.t., 1 h
2: 85 percent / CrO3, aq. H2SO4 / acetone / 4 h / Ambient temperature; ultrasound sonication
3: 86 percent / SOCl2 / 1 h / 60 - 65 °C
4: 86 percent / Et3N / diethyl ether / 1 h / Ambient temperature; ultrasound sonication
View Scheme
参考文献
Newman,M.S. et al.
Journal of the American Chemical Society, 1960 , vol. 82, p. 2498 - 2501
反应条件
1: (i) NaBH4, AlCl3, diglyme, (ii) NaOH, aq. H2O2, EtOH
2: H2SO4, AcOH, CrO3, H2O
3: SOCl2
4: NaNH2, liq. NH3 / diethyl ether
View Scheme
参考文献
Newman,M.S. et al.
Journal of the American Chemical Society, 1960 , vol. 82, p. 2498 - 2501
反应条件
sodium hydroxide; dihydrogen peroxide in tetrahydrofuran
参考文献
Dubois, Jacques-Emile; Zhang, Ben Li; Lion, Claude
Tetrahedron, 1981 , vol. 37, # 24 p. 4189 - 4194
