triphenylphosphine; tetracarbonylbis(μ-chloro)dirhodium(I) in benzene T=150°C; P=36775.4 Torr; 15 h; Further byproducts given. Title compound not separated from byproducts;
1: With tert.-butylhydroperoxide; (OC2H4)(OHC2H4)NC2H4N(C2H4OH)Cu(thiocyanate) in water; acetonitrile T=70°C; P=760.051 Torr; 1 h; 2: With triphenylphosphine in water; acetonitrile regioselective reaction;
参考文献
Journal of Molecular Catalysis A: Chemical, , vol. 350, # 1-2 p. 26 - 34
Me2CuLi*BF3 in diethyl ether T=-35°C; 1 h; Reaction of allylic acetals and ethers with organocopper and cuprate reagents in presence Lewis acids.; Product distributionMechanism;
参考文献
Ghribi, A.; Alexakis, A.; Normant, J. F.
Tetrahedron Letters, 1984 , vol. 25, # 29 p. 3079 - 3082
