9-bora-bicyclo[3.3.1]nonane in hexane under N2, 1,4-pentadiene added to soln. of 9-BBN in n-hexane cooled in ice bath, warmed to room temp., after 3-6 h 9.8 M BH3*SMe2 added, reacted at room temp. for 18-24 h; evapd. in vac. (1 mm Hg), distd. at 0.01 mm Hg;
参考文献
Brown, Herbert C.; Pai, Ganesh G.
Journal of Organometallic Chemistry, 1983 , vol. 250, # 1 p. 13 - 22
dihydrogen peroxide in diethyl ether warming soln. of (C2H5)2O*BH2Cl with soln. of pentadiene-1,4, then oxidn. with alkaline H2O2; 53percent 1,5- and 47percent 1,4- pentanediol;
