coated protease in 3-methyl pentan-3-ol T=21°C; 264 h; Resolution of racemateEnzymatic reaction; enantioselective reaction;

(1S)-10-camphorsulfonic acid

1: platinum; aqueous hydrochloric acid / 60 °C / Hydrogenation 2: (1S)-2-oxo-bornane-sulfonic acid-(10) View Scheme

lithium aluminium tetrahydride; 3-O-cyclohexylmethyl-1,2-O-cyclohexylidene-α-D-glucofuranose in diethyl ether 2.5 h; HeatingLiAlH4 concentration effect on enantiomeric excess; asymmetric reduction of ketones and isoelectronic ketone oximes with LiAlH4-3-O-cyclohexylmethyl-1,2-O-cyclohexylidene-α-D-glucofuranose complex; Product distribution;

1.1: triethylamine / CH2Cl2 / 0.25 h / 20 °C 1.2: 84 percent / acetic acid / CH2Cl2 / 8 h / 20 °C 2.1: sodium azide / dimethylformamide / 5 h / 100 °C 3.1: hydrogen / Pd View Scheme

1,3-dimethoxy-2-propanone; ωTA ATA-117 102907WW; Vibrio fluvialis Vf-ωTA 2100208MW; pyridoxal 5'-phosphate T=30°C; pH=7; 24 h; aq. phosphate bufferEnzymatic reaction;

1,3-dimethoxy-2-propanone; ωTA ATA-117 102907WW; Vibrio fluvialis Vf-ωTA 2100208MW; pyridoxal 5'-phosphate T=30°C; pH=7; 24 h; aq. phosphate bufferEnzymatic reaction;

in dichloromethane T=20°C; 3 h;

carbon in ethyl acetate 5 h; Heating;