hydrogen; dirhodium tetraacetate; diethylphosphinoethane in carbon dioxide T=100°C; 22 h; other solvents, ligands, temp.; various parcial pressures of H2 and CO; Product distribution;
zinc dihydride; Zr catalyst in toluene T=80°C; 3 h; catalyzed hydrozincation of olefins by ZnCl2, oxidation of organozinc compounds formed by O2; Product distribution;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 32, # 5 p. 1080 - 1081
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 5 p. 1195 - 1197
hydrogen; triphenylphosphine; RhH(CO)(triphenylphosphine)3 T=90°C; P=3750.3 Torr; 6.66667 h; var. temp., time, pressure, conc. of catalyst and Ph3P, reaction without Ph3P, half life; Product distributionRate constant;
formaldehyd; RhH2(O2COH)(P(i-Pr)3)2 in tetrahydrofuran T=120°C; 20 h; in autoclave; investigation of reactions of olefins having aliphatic and/or arylic substituents in the presence of varions catalysts; Product distributionMechanism;
