反应条件
in toluene byproducts: acetone; addn. of PMe3 to Mn-complex in toluene at -78°C, warming from -78°C to 0°C, colour changes from light brown to yellow; evapn. of acetone (-60°C, vacuo), fractionated condensation, dissolution of residue in toluene, chromy. (SiO2, toluene, -60°C), elution of C5H5Mn(CO)3 with toluene, elution (Et2O) yields orangeyellow band, evapn., cooling (-20°C);
参考文献
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, , vol. 38, # 11 p. 1497 - 1500
