bis-triphenylphosphine-palladium(II) chloride in N,N,N',N',N'',N''-hexamethylphosphoric triamide
T=120°C; P=15200 Torr; 1 h; also with PdCl2(AsPh3)2, var. time, temp. and catalyst conc.; other organic halides; Product distributionMechanism;
参考文献
Kobayashi, Toshiaki; Tanaka, Masato
Journal of Organometallic Chemistry, 1981 , vol. 205, # 3 p. C27 - C30
in neat (no solvent)
Kinetics; byproducts: CH3OH, CH3OD, CO; heated (heating tape) in a Pyrex cell, backing pressure of <1E-5 mbar, 583 K, excess of oxygen; methanol and formaldehyde detected as transient species; not isolated; IR;
参考文献
Harrison, Philip G.; Ashworth, Andrew; Clark, Edward N.; McManus, James
Journal of the Chemical Society, Faraday Transactions, 1990 , vol. 86, # 24 p. 4059 - 4063
in not given
dropwise addn. of thionyl chloride to tetraalkyltin(IV) compd. under dry N2 atmosphere under ice cooling, warming to room temp., refluxing for 30 min; distn. (removal of excess of SOCl2), cooling resulting liquids, sepn., elem. anal.;
参考文献
Narula, Suraj P.; Sharma, R. K.; Lata, Sneh; Walia, Rita
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1983 , vol. 22, # 3 p. 246 - 247
