in dichloromethane to soln. of triarylstibine in CH2Cl2 added at room temp. soln. of sulfuryl chloride in CH2Cl2; monitored by TLC chromy.; mixt. concd.; hexane added; elem. anal.;
HCl in ethanol; toluene mixt. of SbPh5 and of SbPh2Cl3 hydrate in toluene was allowed to stand at 100°C for 1 h; solvent evapd. and Ph4SbCl recrystd. from water;residue insol. in water dissolved in hot EtOH/HCl; after cooling Ph3SbC l2 was obtained;
参考文献
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, , vol. 29, # 2 p. 89 - 92
