in tetrachloromethane under N2; SbCl5 reacted with Ph3SbS (molar ratio 1:1) in CCl4 at -20°C; detd. by IR and (1)H NMR spectra; mixt. of Ph3SbS and Ph3SbCl2 obtained;
in benzene byproducts: FeCl2; under anhyd. conditions and an atmosphere of dry N2; slow addn. with continuous stirring of the Sb-compd. in benzene to the Fe-compd. in benzene, passing the N2 gas for 24 h with occasional shaking; filtering off the FeCl2 and evapn. of the filtrate, recrystn. of the crude residue from benzene;
参考文献
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, , vol. 21, # 6 p. 619 - 621
in light petroleum passing dry Cl2 gas in a stream of N2 into a soln. of SbPh3 in light petroleum or CCl4; soln. cooled, ppt. filtered off, washed with Et2O; elem. anal.;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , # 8 p. 1545 - 1549
