(R)-(-)-2-辛醇合成路线 （共 140 条）
反应条件
tri-n-butyl-tin hydride in dichloromethane T=18°C; 0.0333333 h; Inert atmospherePhotolysis; enantioselective reaction;
参考文献
Hartung, Jens; Kempter, Irina; Gottwald, Thomas; Schwarz, Michaela; Kneuer, Rainer
Tetrahedron Asymmetry, 2009 , vol. 20, # 18 p. 2097 - 2104
反应条件
tri-n-butyl-tin hydride in dichloromethane T=18°C; 0.416667 h; Inert atmospherePhotolysis; enantioselective reaction;
参考文献
Hartung, Jens; Kempter, Irina; Gottwald, Thomas; Schwarz, Michaela; Kneuer, Rainer
Tetrahedron Asymmetry, 2009 , vol. 20, # 18 p. 2097 - 2104
反应条件
sodium carbonate in methanol T=20°C; 1 h;
参考文献
Ochiai, Masahito; Yoshimura, Akira; Miyamoto, Kazunori; Hayashi, Satoko; Nakanishi, Waro
Journal of the American Chemical Society, 2010 , vol. 132, # 27 p. 9236 - 9239
反应条件
sodium methylate in methanol 12 h;
参考文献
Kaulen, Johannes
Angewandte Chemie, 1987 , vol. 99, # 8 p. 800 - 802
反应条件
methanol; toluene-4-sulfonic acid in dichloromethane 1 h; Ambient temperature;
参考文献
Noe, Christian R.; Knollmueller, M.; Dungler, K.; Miculka, C.; Gaertner, P.
Monatshefte fuer Chemie, 1991 , vol. 122, # 8 p. 705 - 718
反应条件
Novozym 435; potassium tert-butylate; sodium carbonate; [2,3,4,5-Ph4(η5-C4CNH(i-Pr))]Ru(CO)2Cl in toluene T=25°C; 72 h;
参考文献
Journal of Organic Chemistry, , vol. 69, # 6 p. 1972 - 1977
反应条件
1.1: trimethylorthoformate; p-toluenesulfonic acid / 1 h / 0 °C 1.2: benzene / Heating 2.1: CH2Cl2 / -78 - 20 °C 3.1: CH2Cl2; tetrahydrofuran / 1 h / -30 °C 4.1: 72 percent / SmI2; HMPA; MeOH / tetrahydrofuran / 2 h / 25 °C View Scheme
参考文献
Journal of the American Chemical Society, , vol. 125, # 2 p. 428 - 436
反应条件
1: CH2Cl2 / -78 - 20 °C 2: CH2Cl2; tetrahydrofuran / 1 h / -30 °C 3: 72 percent / SmI2; HMPA; MeOH / tetrahydrofuran / 2 h / 25 °C View Scheme
参考文献
Journal of the American Chemical Society, , vol. 125, # 2 p. 428 - 436
反应条件
potassium fluoride; dihydrogen peroxide; potassium hydrogencarbonate in tetrahydrofuran; methanol 12 h; Ambient temperature;
参考文献
Uozumi, Yasuhiro; Kitayama, Kenji; Hayashi, Tamio; Yanagi, Kazunori; Fukuyo, Emiko
Bulletin of the Chemical Society of Japan, 1995 , vol. 68, # 3 p. 713 - 722
反应条件
[(C4Ph4COHOCC4Ph4)(μ-H)][(CO)4Ru2]; Novozym(R) 435; 2,4-dimethylpentan-3-one in toluene T=70°C; P=142.511 Torr; 40 h; Title compound not separated from byproducts;
参考文献
Tetrahedron Asymmetry, , vol. 16, # 9 p. 1603 - 1610
