3-甲基-1,2-丁二烯合成路线 (共 178 条)
反应条件
(Pr4N)[PtCl3(ethylene)] in chloroform
T=60°C; 24 h; Yield given;
参考文献
Renzi, Augusto De; Panunzi, Achille; Saporito, Antonio; Vitagliano, Aldo
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , p. 993 - 996
反应条件
1: aniline With (t-Bu)2P(o-biphenyl)AuCl; silver trifluoromethanesulfonate in 1,4-dioxane
T=20°C; 0.166667 h;
2: 3-methyl-1,2-butadiene in 1,4-dioxane
T=45°C; 24 h; regioselective reaction;
参考文献
Duncan, Alethea N.; Widenhoefer, Ross A.
Synlett, 2010 , # 3 p. 419 - 422
反应条件
(Pr4N)[PtCl3(ethylene)] in chloroform
T=60°C; 24 h; Yield given;
参考文献
Renzi, Augusto De; Panunzi, Achille; Saporito, Antonio; Vitagliano, Aldo
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , p. 993 - 996
反应条件
(Pr4N)[PtCl3(ethylene)] in chloroform
T=60°C; 24 h; Yield given;
参考文献
Renzi, Augusto De; Panunzi, Achille; Saporito, Antonio; Vitagliano, Aldo
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , p. 993 - 996
反应条件
cis-dichloro(1,1-dimethylallene)(triphenylphosphine)platinum(II) in chloroform
T=50°C; 48 h; 60 deg C, other times; other prenylating agent: isoprene - <PdCl2(C2H4)2>; Product distribution;
参考文献
Renzi, Augusto De; Lombardi, Angelina; Panunzi, Achille; Saporito, Antonio
Gazzetta Chimica Italiana, 1988 , vol. 118, # 9 p. 657 - 660
反应条件
cis-dichloro(1,1-dimethylallene)(triphenylphosphine)platinum(II) in chloroform
T=50°C; 48 h; 60 deg C, other times; other prenylating agent: isoprene - <PdCl2(C2H4)2>; Product distribution;
参考文献
Renzi, Augusto De; Lombardi, Angelina; Panunzi, Achille; Saporito, Antonio
Gazzetta Chimica Italiana, 1988 , vol. 118, # 9 p. 657 - 660
反应条件
(η2-propene)Ti(O-i-Pr)2
1.) -50 deg C, 2 h; Yield given. Multistep reaction;
参考文献
Hideura, Daigaku; Urabe, Hirokazu; Sato, Fumie
Chemical Communications (Cambridge, United Kingdom), 1998 , # 2 p. 271 - 272
反应条件
Yield given. Multistep reaction;
参考文献
Yin, Jianguo; Jones, W. M.
Tetrahedron, 1995 , vol. 51, # 15 p. 4395 - 4406
反应条件
1: diethyl ether
2: PhSH, Py / acetone
3: H2 / PtO2 / ethanol
4: aq. KOH
View Scheme
参考文献
Moriconi,E.J.; Kelly,J.F.
Journal of Organic Chemistry, 1968 , vol. 33, # 8 p. 3036 - 3046
反应条件
1: KOtBu
2: H2 / Pt / diethyl ether
View Scheme
参考文献
Ball,W.J. et al.
Journal of the Chemical Society [Section] C: Organic, 1967 , p. 194 - 197