3-甲基-1,2-丁二烯合成路线 （共 178 条）
反应条件
diiodomethane; copper; zinc in diethyl ether
24 h; Heating;
参考文献
Battioni-Savignat,P. et al.
Bulletin de la Societe Chimique de France, 1967 , p. 3929 - 3930
反应条件
diiodomethane; copper; zinc in diethyl ether
24 h; Heating;
参考文献
Battioni-Savignat,P. et al.
Bulletin de la Societe Chimique de France, 1967 , p. 3929 - 3930
反应条件
hydrogenchloride; [2,2']bipyridinyl; Ni(trans,trans,trans-1,5,9-cyclododecatriene)
1.) THF, 20 deg C, 24 h, 2.) Ether, 24 h; Yield given. Multistep reaction;
参考文献
Hoberg, H.; Oster, B. W.
Journal of Organometallic Chemistry, 1984 , vol. 266, # 3 p. 321 - 326
反应条件
1.1: 18 h / 20 °C
2.1: t-BuOCl; triethylamine / tetrahydrofuran / 0.5 h / -78 °C
2.2: tetrahydrofuran / 1.5 h / -78 - 20 °C
2.3: H2O2; NaOH / tetrahydrofuran; H2O / 1 h / 20 °C
3.1: 61 percent / N-bromosuccinimide; acetic acid; formic acid / 0.5 h / 20 °C
4.1: NaOH / ethanol / 24 h / Heating
View Scheme
参考文献
Lindel, Thomas; Braeuchle, Laura; Golz, Gregor; Boehrer, Petra
Organic Letters, 2007 , vol. 9, # 2 p. 283 - 286
反应条件
1: phloroglucinol trimethyl ether With silver tetrafluoroborate; (4-ClPhO)3PAuCl in dichloromethane
0.0333333 h;
2: 3-methyl-1,2-butadiene in dichloromethane
T=20°C; 4 h;
参考文献
Tarselli, Michael A.; Liu, Ann; Gagne, Michel R.
Tetrahedron, 2009 , vol. 65, # 9 p. 1785 - 1789
反应条件
methyllithium; diisopropylamine
参考文献
Creary,X.
Journal of the American Chemical Society, 1977 , vol. 99, # 23 p. 7632 - 7639
反应条件
1: 1.)n-butyllithium / 1.)THF, pentane,-78 deg C, 1 h, 2.)r.t., 4 h
2: Bu3SnH / benzene / Heating; without solvent
View Scheme
参考文献
Apparu, Marcel; Crandall, Jack K.
Journal of Organic Chemistry, 1984 , vol. 49, # 12 p. 2125 - 2130
参考文献
Smirnow
Chem. Zentralbl., 1905 , vol. 76, # I p. 344
反应条件
C21H38AuClNP*C24BF20(1-)*K(1+) in benzene-d6
T=150°C; Markovnikov hydroamination; 30 h; Inert atmosphere;
参考文献
Xiaoming, Zeng; Soleilhavoup, Michele; Bertrand, Guy
Organic Letters, 2009 , vol. 11, # 15 p. 3166 - 3169
反应条件
2,2,6,6-tetramethylpiperidinyl-lithium in diethyl ether
参考文献
Creary,X.
Journal of Organic Chemistry, 1978 , vol. 43, p. 1777 - 1783
