1: 3-hydroxy-1-butene With α-cyclohexylcyclohexanemethanamine; tetrabutylammomium bromide in N,N-dimethyl acetamide T=20°C; Heck reaction; 0.25 h; 2: 2-methoxy-6-bromo-naphthalene With Kaiser oxime-derived complex on resin base in N,N-dimethyl acetamide T=120°C; Heck reaction; 14 h; Further stages. Title compound not separated from byproducts.;
参考文献
Alacid, Emilio; Najera, Carmen
Advanced Synthesis and Catalysis, 2007 , vol. 349, # 17-18 p. 2572 - 2584
1: 3-hydroxy-1-butene With α-cyclohexylcyclohexanemethanamine; tetrabutylammomium bromide in N,N-dimethyl acetamide T=20°C; Heck reaction; 0.25 h; 2: 2-methoxy-6-bromo-naphthalene With Kaiser oxime-derived complex on resin base in N,N-dimethyl acetamide T=120°C; Heck reaction; 24 h; Further stages. Title compound not separated from byproducts.;
参考文献
Alacid, Emilio; Najera, Carmen
Advanced Synthesis and Catalysis, 2007 , vol. 349, # 17-18 p. 2572 - 2584
1: 3-hydroxy-1-butene With α-cyclohexylcyclohexanemethanamine; tetrabutylammomium bromide in water T=20°C; Heck reaction; 0.25 h; 2: 4-hydroxyiodobenzene With Kaiser oxime-derived complex on resin base in water T=120°C; Heck reaction; 5 h; Further stages.;
参考文献
Alacid, Emilio; Najera, Carmen
Advanced Synthesis and Catalysis, 2007 , vol. 349, # 17-18 p. 2572 - 2584
N-(1-chloro-2-methylprop-1-enyl)-N,N-dimethylamine in dichloromethane 1.) 0 deg C; 2.) rt., 3h;
参考文献
Hatch; Nesbitt
Journal of the American Chemical Society, 1950 , vol. 72, p. 727,728
Journal of the American Chemical Society, 1951 , vol. 73, p. 358,359
