1: 1-bromo-1,2,2-trifluoroethene With zinc in N,N-dimethyl-formamide T=20°C; 3 h; 2: chloro-trimethyl-silane With copper(I) bromide Title compound not separated from byproducts;
参考文献
Jairaj, Vinod; Burton, Donald J.
Journal of Fluorine Chemistry, 2003 , vol. 121, # 1 p. 75 - 77
in not given byproducts: H2, CHFCF2; Irradiation (UV/VIS); reaction on UV irradiation in a bomb tube at 25°C;;
参考文献
Clark, H. C.; Furnival, S. G.; Kwon, J. T.
Canadian Journal of Chemistry, 1963 , vol. 41, p. 2889 - 2897
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Gmelin Handbook: Sn: Org.Verb.4, 1.2.2.1.1.4, page 97 - 98
in N,N-dimethyl-formamide byproducts: ZnBr2; N2; slight excess of Zn powder added to alkene soln.; mild exothermic reaction after induction period; removal of excess Zn by press. filtrn. under N2; stirring mixt. at 0 °C for half h with CuBr; final warming to room temp.; (19)F NMR;
参考文献
Journal of the American Chemical Society, , vol. 108, # 14 p. 4229 - 4230
