2,4,6-三甲基苯硼酸合成路线 （共 68 条）
反应条件
potassium acetate; palladium diacetate; silver(l) oxide in dichloromethane
T=20°C; 12 h; Molecular sieve;
参考文献
Feng, Chao; Loh, Teck-Peng
Chemical Communications, 2010 , vol. 46, # 26 p. 4779 - 4781
反应条件
(Dipp2N2C4H6)Pd(η3-cinnamyl)Cl; tetrabutylammomium bromide; sodium hydrogencarbonate in water
Suzuki-Miyaura Coupling; 1 h; Reflux; Catalytic behavior;
参考文献
Kolychev, Eugene L.; Asachenko, Andrey F.; Dzhevakov, Pavel B.; Bush, Alexander A.; Shuntikov, Viacheslav V.; Khrustalev, Victor N.; Nechaev, Mikhail S.
Dalton Transactions, 2013 , vol. 42, # 19 p. 6859 - 6866
反应条件
Suzuki-Miyaura cross coupling;
参考文献
Mita, Tsuyoshi; Michigami, Kenichi; Sato, Yoshihiro
Organic Letters, 2012 , vol. 14, # 13 p. 3462 - 3465
反应条件
potassium phosphate; Pd(II) catalyst in tetrahydrofuran; toluene
T=110°C; Suzuki-Miyaura cross-coupling; 16 h;
参考文献
Altenhoff, Gereon; Goddard, Richard; Lehmann, Christian W.; Glorius, Frank
Journal of the American Chemical Society, 2004 , vol. 126, # 46 p. 15195 - 15201
反应条件
trans-dichloro(1,3-bis-(2,6-diisopentylphenyl)imidazolylidinium)(3-chloro-pyridine); potassium tert-butylate in tert-butyl alcohol
T=65°C; Suzuki-Miyaura coupling; Inert atmosphereMolecular sieve;
参考文献
Organ, Michael G.; Calimsiz, Seluk; Sayah, Mahmoud; Hoi, Ka Hou; Lough, Alan J.
Angewandte Chemie, International Edition, 2009 , vol. 48, # 13 p. 2383 - 2387
反应条件
potassium phosphate; R-Phos; bis(dibenzylideneacetone)-palladium(0) in 1,4-dioxane
T=100°C; Suzuki-Miyaura reaction; 2 h; Inert atmosphere;
参考文献
Hoshi, Takashi; Nakazawa, Taichi; Saitoh, Ippei; Mori, Ayako; Suzuki, Toshio; Sakai, Jun-Ichi; Hagiwara, Hisahiro
Organic Letters, 2008 , vol. 10, # 10 p. 2063 - 2066
反应条件
tripotassium phosphate monohydrate; R-Phos; bis(dibenzylideneacetone)-palladium(0) in tetrahydrofuran
T=50°C; Suzuki coupling; 4 h; Inert atmosphere;
参考文献
Hoshi, Takashi; Saitoh, Ippei; Nakazawa, Taichi; Suzuki, Toshio; Sakai, Jun-Ichi; Hagiwara, Hisahiro
Journal of Organic Chemistry, 2009 , vol. 74, # 10 p. 4013 - 4016
反应条件
1,1'-bis-(diphenylphosphino)ferrocene; potassium phosphate; n-butyllithium; 1,1'-bis(diphenylphosphanyl)ferrocenenickel(II) chloride; potassium iodide
1.) toluene, room temperature, 30 min, 2.) toluene, 80 deg C, 16 h; Yield given. Multistep reaction;
参考文献
Ueda, Masato; Saitoh, Atsushi; Oh-tani, Saori; Miyaura, Norio
Tetrahedron, 1998 , vol. 54, # 43 p. 13079 - 13086
反应条件
tetrakis(triphenylphosphine) palladium(0); TlOH in N,N-dimethyl acetamide
12 h; Ambient temperature;
参考文献
Anderson, James C.; Namli, Hilmi; Roberts, Craig A.
Tetrahedron, 1997 , vol. 53, # 44 p. 15123 - 15134
反应条件
potassium hydroxide; palladium dichloride in water
T=20 - 75°C; Suzuki-Miyaura coupling; 5 h;
参考文献
Korolev, Dmitrii N.; Bumagin, Nikolay A.
Tetrahedron Letters, 2006 , vol. 47, # 25 p. 4225 - 4229
