[1,3-双(二苯基膦基)丙烷]二氯化钯(II)合成路线 （共 7 条）
反应条件
1,3-bis-(diphenylphosphino)propane in benzene stirring (30 min, N2-atmosphere); pptn. on pentane addn., filtration, washing (pentane), drying (vac., room temp.), dissoln. in DMF (85°C), filtration, cooling, Et2O addn., crystn. (ice bath);
参考文献
Komoroski, Richard A.; Magistro, Angelo J.; Nicholas, Paul P.
Inorganic Chemistry, 1986 , vol. 25, p. 3917 - 3925
反应条件
in chloroform-d1 Parr bomb (3.4 atm CO, room temp., 1 d); removal of excess CO, filtration to remove any metallic Pd;
参考文献
Kacker, Smita; Kim, Jang Sub; Sen, Ayusman
Angewandte Chemie - International Edition, 1998 , vol. 37, # 9 p. 1251 - 1253
反应条件
in dichloromethane; acetonitrile byproducts: AgCl; stirring (15 min); filtration, solvent removal, drying (reduced pressure, 1 d);
参考文献
Angewandte Chemie - International Edition, , vol. 37, # 9 p. 1251 - 1253
参考文献
Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, , vol. 37, # 10 p. 904 - 907
反应条件
in tetrahydrofuran; ethanol stirring for 2 h; evapn., washing with H2O, drying at 80°C for 12 h;
参考文献
Housecroft, Catherine E.; Shaykh, Bilal A.; Rheingold, Arnold L.; Haggerty, Brian S.
Inorganic Chemistry, 1991 , vol. 30, p. 125 - 130
反应条件
in diethyl ether byproducts: CH3COOH; (Ar), mixed, stirred for 10 min, mixed with DPPPr dropwize with stirring, pptd., stirred for 1 h; filtered, washed with dry ethylether, dried in vac.;
参考文献
Luo, He-Kuan; Kou, Yuan; Wang, Xi-Wen; Li, Da-Gang
Journal of Molecular Catalysis A: Chemical, 2000 , vol. 151, # 1-2 p. 91 - 113
反应条件
in dichloromethane under N2, addn. of complex in CH2Cl2 to soln. of ligand in CH2Cl2, stirred for 25°C for 2 h, white pptn.; evapd. under reduced press., addn. of toluene, heated under reflux for 4 h, pptn., filtered, dried in vac.;
参考文献
Polyhedron, , vol. 12, p. 721 - 730
