α-D(+)-五乙酰葡萄糖合成路线 （共 168 条）
反应条件
bis(tri-n-butyltin)oxide in benzene 24 h; Heatingvar. solv, temp, and time; Yield given. Yields of byproduct given;
参考文献
Watanabe, Kazuko; Itoh, Kiyotaka; Araki, Younosuke; Ishido, Yoshiharu
Carbohydrate Research, 1986 , vol. 154, p. 165 - 176
反应条件
lipase from Pseudomonas fluorescens; phosphate buffer pH 7 in acetonitrile var. pH, var. lipases; Product distribution;
参考文献
Bastida, Agatha; Fernandez-Lafuente, Roberto; Fernandez-Lorente, Gloria; Guisan, Jose M.; Pagani, Giuseppe; Terreni, Marco
Bioorganic and Medicinal Chemistry Letters, 1999 , vol. 9, # 4 p. 633 - 636
反应条件
boron trifluoride diethyl etherate in dichloromethane T=0°C; 8 h; Product distribution / selectivity;
参考文献
Davis, Benjamin Guy; Fairbanks, Antony John; Reichhardt, Niels Christian; Angadiparambil, Vinod Unni
Patent: US2009/176970 A1, 2009 ;
Location in patent: Page/Page column 7; 18 ;
反应条件
1: hydrogen bromide; acetic acid 2: silver carbonate / acetonitrile / 8 h / 25 °C 3: triethanolamine; palladium diacetate / 4 h / 100 °C View Scheme
参考文献
Csuk, Rene; Albert, Sabrina
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2011 , vol. 66, # 3 p. 311 - 316
反应条件
aluminium trichloride in dichloromethane T=50°C; 2 h;
参考文献
Rajanikanth, B.; Seshadri, R.
Tetrahedron Letters, 1987 , vol. 28, # 20 p. 2295 - 2296
反应条件
1: 60 percent / AlCl3 / CH2Cl2 / 20 h / Heating 2: 80 percent / AlCl3, dichloroaluminium acetate / CH2Cl2 / 2 h / Heating View Scheme
参考文献
Weng, Shiue-Shien; Li, Chia-Ling; Liao, Chun-Sheng; Chen, Ting-An; Huang, Chao-Cheih; Hung, Kuo-Tung
Journal of Carbohydrate Chemistry, 2010 , vol. 29, # 8-9 p. 429 - 440
反应条件
1.1: hydrogen bromide; acetic acid / 2 h / 20 °C / Industry scale
1.2: 2 h / 0 - 5 °C / Industry scale
2.1: sodium methylate / methanol / 5 - 20 °C / pH 9 - 9.5 / Industry scale
2.2: 5 h / Reflux; Molecular sieve; Industry scale
2.3: 0 - 20 °C
3.1: sodium hydrogencarbonate / N,N-dimethyl-formamide / 20 - 122 °C / Industry scale
4.1: potassium hydroxide / tetrabutylammomium bromide / toluene; 1-methyl-pyrrolidin-2-one / 0 - 20 °C / Industry scale
View Scheme
参考文献
Apicore, LLC
Patent: US2013/5954 A1, 2013 ;
反应条件
in diethyl ether
Substitution;
参考文献
Ohmori, Osamu; Takayama, Hiromitsu; Aimi, Norio
Tetrahedron Letters, 1999 , vol. 40, # 27 p. 5039 - 5042
