in ammonia
heating in a sealed tube at 180-185°C for 2 h;; precipitate; sucking off; washed with cold H2O; sepn. of Cu by digesting with very diluted H2SO4 soln.;;
参考文献
Vittenet, H.
Bulletin de la Societe Chimique de France, 1899 , vol. 21, p. 261 - 262
Full Text Show Details
Gmelin Handbook: Cu: MVol.B2, 103, page 850 - 852
in neat (no solvent, solid phase)
byproducts: H2O, CO2; on heating to temp. higher 290°C; DTG;
参考文献
Kondrat, Simon A.; Davies, Thomas E.; Zu, Zhongling; Boldrin, Paul; Bartley, Jonathan K.; Carley, Albert F.; Taylor, Stuart H.; Rosseinsky, Matthew J.; Hutchings, Graham J.
Journal of Catalysis, 2011 , vol. 281, # 2 p. 279 - 289
in ethanol
hot soln. of Cu-salt in EtOH treated with a hot soln. of thiosemicarbazone in ethanol, mixture refluxed for 30 min, left to cool; filtered, washed with ethanol and ether; elem. anal.;
参考文献
Iskander, M. F.; El-Sayed, L.; El-Toukhy, A.
Journal of Inorganic and Nuclear Chemistry, 1980 , vol. 42, p. 1145 - 1150
potassium carbonate; acetic acid in N-methyl-acetamide; water
参考文献
Sterling Drug Inc.
Patent: US4515980 A1, 1985 ;
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反应条件
triethylamine in methanol
refluxed for 1 h; removal of solvent in vac., addn. of acetone and triethylamine, left overnight in the refrigerator, filtered off, dried over P4O10; elem. anal.;
参考文献
Kasprzyk, Stanislaw P.; Kolinski, Ryszard A.; Mrozinski, Jerzy
Polyhedron, 1988 , vol. 7, p. 1053 - 1062
