1-烯丙基-1-甲氧基环己烷合成路线 （共 7 条）
反应条件
50 wt silicomolybdic acid/SiO2 in acetonitrile
T=20°C; Hosomi-Sakurai reaction; 0.16 h;
参考文献
Murugan, Kaliyappan; Srimurugan, Sankareswaran; Chen, Chinpiao
Tetrahedron, 2011 , vol. 67, # 31 p. 5621 - 5629
反应条件
InOTf in toluene
T=25°C; 19 h; Inert atmosphere;
参考文献
Schneider, Uwe; Dao, Hai T.; Kobayashi, Shu
Organic Letters, 2010 , vol. 12, # 11 p. 2488 - 2491
反应条件
trimethylsilyl trifluoromethanesulfonate; 1-(n-butyl)-3-methylimidazolium triflate
T=20°C; 1.33333 h;
参考文献
Anzalone, Peter W.; Mohan, Ram S.
Synthesis, 2005 , # 16 art. no. M02005SS, p. 2661 - 2663
反应条件
trimethylsilyl iodide in dichloromethane
1.) -40 deg C, 30 min, 2.) 0 deg C, 4 h;
参考文献
Sakurai, Hideki; Sasaki, Koshi; Hayashi, Josaburo; Hosomi, Akira
Journal of Organic Chemistry, 1984 , vol. 49, # 15 p. 2808 - 2809
反应条件
Fe(OTs)3*6H2O in acetonitrile
T=20°C; 5 h;
参考文献
Spafford, Matthew J.; Anderson, Erin D.; Lacey, Joshua R.; Palma, Ann C.; Mohan, Ram S.
Tetrahedron Letters, 2007 , vol. 48, # 49 p. 8665 - 8667
反应条件
1: allylcyclohexanol With sodium hydride in tetrahydrofuran
2 h; Heating;
2: dimethyl sulfate in tetrahydrofuran
Heating;
参考文献
Mihovilovic, Marko D.; Spina, Markus; Mueller, Bernhard; Stanetty, Peter
Monatshefte fur Chemie, 2004 , vol. 135, # 7 p. 899 - 909
反应条件
1: 89 percent / trimethylsilyl triflate / CH2Cl2 / 3 h / -78 °C
2: 81 percent / trimethylsilyl triflate / CH2Cl2 / 18 h / -60 - -45 °C
View Scheme
参考文献
Noyori, R.; Murata, S.; Suzuki, M.
Tetrahedron, 1981 , vol. 37, # 23 p. 3899 - 3910
