sodium hydride in N,N-dimethyl-formamide; benzene
2 h; Ambient temperature;
参考文献
Murakami, Yukito; Hisaeda, Yoshio; Ozaki, Toshiaki; Tashiro, Takako; Ohno, Teruhisa; et al.
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 1 p. 311 - 324
1: methyl malonic acid diethylester With sodium hydride in tetrahydrofuran
T=0°C;
2: (E)-2-butenyl triflate With substituted-biphenyl-phosphoramideite; [(η3-allyl)Pd(OAc)]2 in tetrahydrofuran
T=20°C; 2 h; Title compound not separated from byproducts;
参考文献
Boele, Maarten D. K.; Kamer, Paul C. J.; Lutz, Martin; Spek, Anthony L.; De Vries, Johannes G.; Van Leeuwen, Piet W. N. M.; Van Strijdonck, Gino P. F.
Chemistry - A European Journal, 2004 , vol. 10, # 24 p. 6232 - 6246
1: methyl malonic acid diethylester With sodium hydride in tetrahydrofuran
T=0°C;
2: trans-crotonyl chloride With substituted-biphenyl-phosphoramideite; [(η3-allyl)Pd(OAc)]2 in tetrahydrofuran
T=20°C; 2 h; Title compound not separated from byproducts;
参考文献
Boele, Maarten D. K.; Kamer, Paul C. J.; Lutz, Martin; Spek, Anthony L.; De Vries, Johannes G.; Van Leeuwen, Piet W. N. M.; Van Strijdonck, Gino P. F.
Chemistry - A European Journal, 2004 , vol. 10, # 24 p. 6232 - 6246
1: methyl malonic acid diethylester With sodium hydride in tetrahydrofuran
T=0°C;
2: (E)-crotyl acetate With substituted-biphenyl-phosphoramideite; [(η3-allyl)Pd(OAc)]2 in tetrahydrofuran
T=20°C; 2 h; Title compound not separated from byproducts;
参考文献
Boele, Maarten D. K.; Kamer, Paul C. J.; Lutz, Martin; Spek, Anthony L.; De Vries, Johannes G.; Van Leeuwen, Piet W. N. M.; Van Strijdonck, Gino P. F.
Chemistry - A European Journal, 2004 , vol. 10, # 24 p. 6232 - 6246
