2,6-二甲基-5-庚烯-2-醇合成路线 （共 35 条）
参考文献
Givaudan Corporation
Patent: US4634548 A1, 1987 ;
反应条件
potassium permanganate; water; copper(II) sulfate in dichloromethane 1.) reflux, 5 min, 2.) RT, 4 h;
参考文献
Baskaran, Sundarababu; Islam, Imadul; Vankar, Padma S.; Chandrasekaran, Srinivasan
Journal of the Chemical Society, Chemical Communications, 1990 , # 23 p. 1670 - 1671
反应条件
sodium hydrogen sulphate; tin(IV) chloride 2) CH2Cl2, 20 - 30 min, 0 deg C; 3) room temperature, 6 h, CH2Cl2; Yield given. Multistep reaction;
参考文献
Cookson, Richard C.; Mirza, Nasir A.
Synthetic Communications, 1981 , vol. 11, # 4 p. 299 - 302
反应条件
1: pyridine / 160 °C 2: acetic acid; diethyl ether; sulfuric acid / 350 °C / Erwaermen das Reaktionsprodukt mit methanol. Kalilauge View Scheme
参考文献
Gruetter; Schinz
Helvetica Chimica Acta, 1952 , vol. 35, p. 1656,1659
反应条件
nickel T=175 - 185°C; Hydrogenation.unter gewoehnlichem Druck;
参考文献
Escourrou
Bulletin de la Societe Chimique de France, 1928 , vol. <4>43, p. 1108
Full Text Show Details
Grignard; Escourrou
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1923 , vol. 177, p. 96
反应条件
nickel pumice stone T=160 - 170°C; P=14 Torr; Hydrogenation;
参考文献
Escourrou
Bulletin de la Societe Chimique de France, 1928 , vol. <4>43, p. 1108
Full Text Show Details
Grignard; Escourrou
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1923 , vol. 177, p. 96
参考文献
Kennedy,J.P.; Melby,E.G.
Journal of Organic Chemistry, 1975 , vol. 40, p. 1099 - 1101
参考文献
Kononowicz
Journal fuer Praktische Chemie (Leipzig), 1884 , vol. <2>30, p. 408
反应条件
1: 26 percent / SOCl2, pyridine / benzene / 0 - 20 °C
2: 25 percent / tetraphenylporphine, O2 / CH2Cl2 / 4 h / -50 °C
3: triphenylphosphine
View Scheme
参考文献
Carless, Howard A.J.; Batten, Richard J.
Tetrahedron Letters, 1982 , vol. 23, # 45 p. 4735 - 4738
反应条件
1: 22 percent / SOCl2, pyridine / benzene / 0 - 20 °C
2: 21 percent / tetraphenylporphine, O2 / CH2Cl2 / 2 h / -50 °C
3: triphenylphosphine
View Scheme
参考文献
Carless, Howard A.J.; Batten, Richard J.
Tetrahedron Letters, 1982 , vol. 23, # 45 p. 4735 - 4738
